Crystal growth, crystal structure and linear optical properties of the non-centrosymmetric ammonium bis(nitrilotriacetato)zirconate and hafnate, (NH4)2[Zr{N(CH2COO)3}2] and (NH4)2[Hf{N(CH2COO)3}2]

被引：0
|
作者：
Held, P
Listl, B
Tillmanns, E
Ahrweiler, S
Hellwig, H
Bohaty, L
机构：
[1] Univ Cologne, Inst Kristallog, D-50674 Cologne, Germany
[2] Univ Vienna, Inst Kristallog & Mineral, A-1090 Vienna, Austria
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2000年 / 215卷 / 01期
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D O I：
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中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Large single crystals of ammonium bis(nitrilotriacetato)zirconate, (NH4)(2)[Zr{N(CH2COO)(3)}(2)] (to be written (NH4)(2)[Zr(NTA)(2)]), were grown. Linear optical properties were measured (indices of refraction and transparency range) and the phase matching conditions for second harmonic generation process were determined. Crystal structures of the zirconate and the isomorphic hafnate were solved from single crystal X-ray diffraction data (P3(1,2)21; Z = 3; Zr: a = 9.582(1) Angstrom, c = 16.611(4) Angstrom, Hf: a = 9.5846(5) Angstrom, c = 16.5920(8) Angstrom) and the geometry of the complex groups [Zr(NTA)(2)](2-) and [Hf(NTA)(2)](2-) was analysed.
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页码：65 / 71
页数：7
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