Luminescence of Terbium (III) Complexes Incorporated in Carboxylic Acid Functionalized Polystyrene/BaTiO3 Nanocomposites

被引：13

作者：

Cao, Xuan Thang ^{[1
]}

Showkat, Ali Md ^{[1
]}

Lee, Won-Ki ^{[2
]}

Lim, Kwon Taek ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Imaging Syst Engn, Busan 608737, South Korea

[2] Pukyong Natl Univ, Dept Polymer Engn, Busan 608737, South Korea

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2015年 / 622卷 / 01期

关键词：

INITIATED RAFT POLYMERIZATION; PHOTOLUMINESCENCE; BATIO3; NANOCRYSTALS;

D O I：

10.1080/15421406.2015.1096988

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Luminescence nanocomposites based on barium titanate nanoparticles (BaTiO3), polystyrene (PSt), and terbium ion (Tb3+) were synthesized by using a combination of reversible addition fragmentation chain transfer polymerization, Friedel-Crafts alkylation reaction and coordination chemistry. The modification of the surface of BaTiO3 was conducted by an exchange process with S-benzyl S-trimethoxysilylpropyltrithiocarbonate to anchor macro-initiators for the polymerization of styrene. Subsequently, PSt grafted barium titanate was functionalized by the substitution reaction between 4-(chloromethyl) benzoic acid and PSt to produce hybrids, BaTiO3-g-PSt -COOH. The coordination of the hybrids with Tb3+ ions in the presence of 1,10-phenanthroline (Phen) afforded fluorescent Tb3+ tagged carboxylic acid functionalized polystyrene/barium titanate (BaTiO3-g-PSt-Tb3+-Phen). FT-IR, XRD, TGA, and SEM analyses revealed the formation of BaTiO3-g-PSt-Tb3+-Phen hybrids. The optical properties of BaTiO-3-g-PSt-Tb3+-Phen were investigated by using fluorescence spectroscopy. © 2015 Taylor & Francis Group, LLC.

引用

页码：36 / 43

页数：8

共 11 条

[1] Poly(allyl methacrylate) functionalized hydroxyapatite nanocrystals via the combination of surface-initiated RAFT Polymerization and thiol-ene protocol: A potential anticancer drug nanocarrier [J].