Poly(N,N′-dichloro-N-ethylbenzene-1,3-disulfonamide) and N,N,N′,N′-Tetrachlorobenzene-1,3-disulfonamide as Novel Reagents for the Synthesis of N-Chloroamines, Nitriles and Aldehydes

被引：34

作者：

Ghorbani-Vaghei, Ramin ^{[1
]}

Veisi, Hojat ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 65174, Iran

来源：

SYNTHESIS-STUTTGART | 2009年 / 06期

关键词：

TCBDA; PCBS; dichloroamines; nitriles; alcohols; NICKEL-CATALYZED OXIDATION; ONE-POT SYNTHESIS; PRIMARY AMINES; ORGANIC-SYNTHESIS; TETRABUTYLAMMONIUM PEROXYDISULFATE; CORRESPONDING NITRILES; PRIMARY ALCOHOLS; TERTIARY-AMINES; PRIMARY AMIDES; CONVERSION;

D O I：

10.1055/s-0028-1087967

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The applications of poly(N,N'-dichloro-N-ethylbenzene-1,3-disulfonamide) (PCBS) and N,N,N',N'-tetrachlorobenzene-1,3-disulfonamide (TCBDA) as novel reagents for the preparation of N,N-dichloroamines, nitriles, and aldehydes from primary amines under various conditions are described. Also, a simple and effective procedure for the direct oxidative conversion of primary alcohols into nitriles was successfully carried Out with TCBDA and PCBS in aqueous ammonia.

引用

页码：945 / 950

页数：6

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