An Aqueous Dual-Ion Battery Cathode of Mn3O4 via Reversible Insertion of Nitrate

被引：110

作者：

Jiang, Heng ^{[1
]}

Wei, Zhixuan ^{[1
,2
]}

Ma, Lu ^{[3
,4
]}

Yuan, Yifei ^{[3
,4
]}

Hong, Jessica J. ^{[1
]}

Wu, Xianyong ^{[1
]}

Leonard, Daniel P. ^{[1
]}

Holoubek, John ^{[1
]}

Razink, Joshua James ^{[5
]}

Stickle, William F. ^{[6
]}

Du, Fei ^{[2
]}

Wu, Tianpin ^{[3
,4
]}

Lu, Jun ^{[3
,4
]}

Ji, Xiulei ^{[1
]}

机构：

[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA

[2] Jilin Univ, Coll Phys, Minist Educ, Key Lab Phys & Technol Adv Batteries, Changchun 130012, Jilin, Peoples R China

[3] Argonne Natl Lab, Adv Photon Sources, Chem Sci & Engn Div, Lemont, IL 60439 USA

[4] Argonne Natl Lab, Adv Photon Sources, Xray Sci Div, Lemont, IL 60439 USA

[5] Univ Oregon, CAMCOR, Eugene, OR 97403 USA

[6] Hewlett Packard Corp, 1000 NE Circle Blvd, Corvallis, OR 97330 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 16期

基金：

美国国家科学基金会;

关键词：

aqueous electrolyte; batteries; dual-ion; manganese; quartz crystal microbalance; RAY-ABSORPTION SPECTROSCOPY; ELECTROCHEMICAL INTERCALATION; RECHARGEABLE BATTERY; ENERGY-STORAGE; HYDRATED IONS; N-TYPE; GRAPHITE; ELECTRODE; ANIONS; BEHAVIOR;

D O I：

10.1002/anie.201814646

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report reversible electrochemical insertion of NO3- into manganese(II, III) oxide (Mn3O4) as a cathode for aqueous dual-ion batteries. Characterization by TGA, FTIR, EDX, XANES, EXAFS, and EQCM collectively provides unequivocal evidence that reversible oxidative NO3- insertion takes place inside Mn3O4. Ex situ HRTEM and corresponding EDX mapping results suggest that NO3- insertion de-crystallizes the structure of Mn3O4 Kinetic studies reveal fast migration of NO3- in the Mn3O4 structure. This finding may open a new direction for novel low-cost aqueous dual-ion batteries.

引用

页码：5286 / 5291

页数：6

共 66 条

[1]

[Anonymous], 2014, ANGEW CHEM

[2] Mn3O4 and γ-MnOOH powders, preparation, phase composition and XPS characterisation [J].

Ardizzone, S ;

Bianchi, CL ;

Tirelli, D .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 134 (03) :305-312

[3] A Dual-Ion Battery Cathode via Oxidative Insertion of Anions in a Metal-Organic Framework [J].

Aubrey, Michael L. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (42) :13594-13602

[4]

Augustyn V, 2013, NAT MATER, V12, P518, DOI [10.1038/NMAT3601, 10.1038/nmat3601]

[5] Supercritical fluid processing of nitric acid treated nitrogen doped graphene with enhanced electrochemical supercapacitance [J].

Balaji, Suresh ;

Sathish, M. .

RSC ADVANCES, 2014, 4 (94) :52256-52262

[6] REVERSIBLE ELECTROCHEMICAL INSERTION OF ANIONS IN POLY-PARA-PHENYLENE FROM AQUEOUS-ELECTROLYTES [J].

BECK, F ;

PRUSS, A .

ELECTROCHIMICA ACTA, 1983, 28 (12) :1847-1855

[7] Does Size really Matter? New Insights into the Intercalation Behavior of Anions into a Graphite-Based Positive Electrode for Dual-Ion Batteries [J].

Beltrop, Kolja ;

Meister, Paul ;

Klein, Sven ;

Heckmann, Andreas ;

Gruenebaum, Mariano ;

Wiemhoefer, Hans-Dieter ;

Winter, Martin ;

Placke, Tobias .

ELECTROCHIMICA ACTA, 2016, 209 :44-55

[8] Mixed valence nanostructured Mn3O4 for supercapacitor applications [J].

Bose, Vipin C. ;

Biju, V. .

BULLETIN OF MATERIALS SCIENCE, 2015, 38 (04) :865-873

[9] Manganese Oxide/Carbon Yolk-Shell Nanorod Anodes for High Capacity Lithium Batteries [J].

Cai, Zhengyang ;

Xu, Lin ;

Yan, Mengyu ;

Han, Chunhua ;

He, Liang ;

Hercule, Kalele Mulonda ;

Niu, Chaojiang ;

Yuan, Zefan ;

Xu, Wangwang ;

Qu, Longbing ;

Zhao, Kangning ;

Mai, Liqiang .

NANO LETTERS, 2015, 15 (01) :738-744

[10] OBSERVATION AND CHARACTERIZATION BY SCANNING TUNNELING MICROSCOPY OF STRUCTURES GENERATED BY CLEAVING HIGHLY ORIENTED PYROLYTIC-GRAPHITE [J].

CHANG, HP ;

BARD, AJ .

LANGMUIR, 1991, 7 (06) :1143-1153

← 1 2 3 4 5 6 7 →