The effects of dynamic crosslinking on rheological, mechanical and dynamic mechanical properties of high density polyethylene (HDPE) and acrylonitrile butadiene rubber (NBR) blends have been evaluated with special reference to the effect of dosage of crosslinking agent. The morphology has been studied using scanning electron microscope. Both the microscopy and dynamic mechanical analysis indicate that the blends are immiscible and form two-phase structures. But it is evident that dynamic vulcanisation can be employed as a technological compatibilisation technique to get finer and stable morphology and improved mechanical properties. The rheological studies reveal that the dynamically vulcanised samples could be processed like thermoplastics. (C) 1999 Elsevier Science Ltd. All rights reserved.
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Univ Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil
Univ Fed Rio de Janeiro, Dept Engn Met & Mat, Ctr Tecnol, BR-21941972 Rio De Janeiro, RJ, BrazilUniv Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil
Soares, Bluma G.
Freitas, Juliana B.
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Univ Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil
Furnas Centrais Eletr, Eletrobraas, Rio De Janeiro, BrazilUniv Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil
Freitas, Juliana B.
Silva, Adriana A.
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Univ Fed Rio de Janeiro, Escola Quim, BR-21941909 Rio De Janeiro, RJ, BrazilUniv Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil
Silva, Adriana A.
Sirqueira, Alex S.
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Ctr Univ Estadual Zona Oeste, Av Manuel Caldeira de Alvarenga 1203, BR-23070200 Rio De Janeiro, RJ, BrazilUniv Fed Rio de Janeiro, Inst Macromol, Ctr Tecnol, BR-21941598 Rio De Janeiro, RJ, Brazil