Properties and influence of microstructure and crystal defects in Fe2VAl modified by laser surface remelting

被引:23
作者
Gomell, Leonie [1 ]
Roscher, Moritz [1 ]
Bishara, Hanna [1 ]
Jaegle, Eric A. [1 ,2 ]
Scheu, Christina [1 ]
Gault, Baptiste [1 ,3 ]
机构
[1] Max Planck Inst Eisenforsch GmbH, Max Planck Str 1, D-40237 Dusseldorf, Germany
[2] Univ Bundeswehr Munchen, Inst Werkstoffkunde, Werner Heisenberg Weg 39, D-85577 Neubiberg, Germany
[3] Imperial Coll London, Royal Sch Mines, Dept Mat, London, England
基金
欧洲研究理事会;
关键词
Thermoelectric materials; Atom probe tomography; Microstructure; Grain boundary defects; Laser surface remelting; THERMOELECTRIC PROPERTIES; BISMUTH TELLURIDE; ANTISITE DEFECTS; HOT-CRACKING; PERFORMANCE; BOUNDARIES;
D O I
10.1016/j.scriptamat.2020.10.050
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Laser surface remelting can be used to manipulate the microstructure of cast materials. Here, we present a detailed analysis of Fe2VAl following laser surface remelting. Within the melt pool, elongated grains grow nearly epitaxially from the heat-affected zone. These grains are separated by low-angle grain bound-aries with 1 degrees-5 degrees misorientations. Segregation of vanadium, carbon, and nitrogen at grain boundaries and dislocations is observed using atom probe tomography. The local electrical resistivity was measured by an in-situ four-point-probe technique. A smaller increase in electrical resistivity is observed at these low angle grain boundaries compared to high-angle grain boundaries in a cast sample. This indicates that grain boundary engineering could potentially be used to manipulate thermoelectric properties. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:153 / 157
页数:5
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