Synthesis and characterization of phytochemical fabricated zinc oxide nanoparticles with enhanced antibacterial and catalytic applications

被引:75
作者
Ali, Jawad [1 ]
Irshad, Rabia [1 ]
Li, Baoshan [1 ]
Tahir, Kamran [2 ]
Ahmad, Aftab [1 ]
Shakeel, Muhammad [1 ]
Khan, Naeem Ullah [1 ]
Khan, Zia Ul Haq [3 ]
机构
[1] Beijing Univ Chem Technol, Sch Sci, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Gomal Univ, Inst Chem Sci, Dera Ismail Khan, KP, Pakistan
[3] COMSATS Inst Informat Technol, Dept Environm Sci, Vehari 61100, Pakistan
基金
中国国家自然科学基金;
关键词
Zinc oxide nanoparticles; Green synthesis; Conyza canadensis; Antibacterial activity; Catalytic reduction; PHENOLIC AZO DYES; GREEN SYNTHESIS; SILVER NANOPARTICLES; ZNO NANOPARTICLES; LEAF EXTRACT; ELECTROCHEMICAL DEGRADATION; REDUCTION; BACTERIA;
D O I
10.1016/j.jphotobiol.2018.05.006
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A "green route" to fabricate nanoparticles has emerged as a revolutionary approach. The reported work presents a green approach to synthesize ZnO nanoparticles using Conyza canadensis plant leaves extract. The synthesis of ZnO was conducted at two different temperatures i.e. 30 degrees C and 80 degrees C. ZnO nanoparticles prepared at 80 degrees C were smaller in size and exhibited spherical morphology. The prepared nanomaterials were examined for the reduction of organic dyes i.e. methylene blue and methyl orange. The fabricated ZnO nanoparticles synthesized at 80 degrees C were found to be highly active for the reduction of aforementioned dyes with 94.5% reduction of MO and 85.3% reduction of MB in 45 min and 20 min respectively. The rate constant (k) for this reduction of MO was found to be 5.781 x 10(-3) s(-1) in the absence of a catalyst and 5.843 x 10(-2) s(-1) in the presence of ZnO NPs catalyst. The rate constant (k) for the reduction of MB was found to be 4.7 x 10(-3) s(-1) in the absence of a catalyst and 9.936 x 10(-3) s(-1) in the presence of ZnO NPs catalyst. ZnO nanoparticles synthesized at 80 degrees C were examined for their antibacterial activity. The biogenic ZnO nanoparticles exhibited strong antibacterial activity against E. colt and S. aureus with a zone of inhibition (16 mm) and (14 mm) respectively. This high antibacterial and catalytic activity of biogenic ZnO nanoparticles can be attributed to its small size, good dispersion, and welldefined morphology.
引用
收藏
页码:349 / 356
页数:8
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