The acceleration of Zn(II) electroreduction on mercury electrode by 1,5-diaminonaphthalene and N,N′-diphenylthiourea, catalytically passive in the aqueous solution, in binary mixtures

被引：0

作者：

Marczewska, B ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland

来源：

ELECTROANALYSIS | 1999年 / 11卷 / 15期

关键词：

reduction of Zn-II; binary mixtures; acceleration;

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The effect of 1,5-diaminonaphthalene (DAN) in water-methanol (MeOH) mixture and N,N'-diphenylthiourea (DFTU) in water-ethanol (EtOH) mixture on the electroreduction of Zn-II on the mercury electrode is discussed. Both substances have no effect on the Zn-II electroreduction process in the aqueous solution but they accelerate the process in water-alcohol mixtures. A probable mechanism of this process has been presented.

引用

页码：1101 / 1107

页数：7

共 7 条

[1] The accelerationof Zn(II) electroreduction on mercury electrode by 1,5-diaminonaphthalene and N,N′-diphenylthiourea, catalytically passive in the aqueous solution, in binary mixtures
Faculty of Chemistry, Maria Curie-Sklodowska Univ., PL-20-031 Lublin, Poland
Electroanalysis, 15 (1101-1107):
[2] Complexation of N-tris[(1,2-dicarboxyethoxy)ethyl]amine with Ca(II), Mn(II), Cu(II) and Zn(II) in aqueous solution
Hyvönen, H
Orama, M
Alén, P
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[3] KINETICS AND MECHANISM OF DISSOCIATION AND ELECTROREDUCTION (AT DME) OF THE COPPER(II) AND NICKEL(II) COMPLEXES OF THE MACROCYCLIC LIGAND 1,3,6,9,11,14-HEXA-AZACYCLOHEXADECANE ([16]-ANE-N6) IN AQUEOUS-SOLUTION
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[5] Fluorescent chemosensor for mercury(II) cations in an aqueous solution based on 4-acetylamino-1, 8-naphthalimide derivative containing the N-phenylazadithia-15-crown-5-ether receptor
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Russian Chemical Bulletin, 2021, 70 : 1939 - 1945
[6] Complexation of [S,S,S]- and [R,S,R]-isomers of N-bis[2-(1,2-dicarboxyethoxy)ethyl] aspartic acid with Mg(II), Ca(II), Mn(II), Fe(III), Cu(II) and Zn(II) ions in aqueous solution
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JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (16) : 2515 - 2527
[7] MECHANISMS OF CHARGE-TRANSFER AT THE SEMICONDUCTOR-ELECTROLYTE INTERFACE .1. KINETICS OF ELECTROREDUCTION AT DARK OF FE(CN)63- AND IRCL62- IN AQUEOUS-SOLUTION ON A SINTERED NB-DOPED N-SRTIO3 ELECTRODE - INFLUENCE OF PH
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JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (02) : 326 - 336

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