Z-scheme Ag3PO4/POM/GO heterojunction with enhanced photocatalytic performance for degradation and water splitting

被引:43
作者
Liu, Guodong [1 ]
Zhao, Xinfu [2 ]
Zhang, Jian [1 ]
Liu, Shaojie [3 ]
Sha, Jingquan [1 ]
机构
[1] Jining Univ, Dept Chem & Chem Engn, Qufu 273100, Peoples R China
[2] QiLu Univ Technol, Shandong Acad Sci, Shandong Prov Key Lab Special Silicone Containing, Jinan 250100, Shandong, Peoples R China
[3] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
关键词
DRIVEN HYDROGEN EVOLUTION; AG3PO4; SUBMICRO-CUBES; VISIBLE-LIGHT; FACILE SYNTHESIS; SELECTIVE GROWTH; NANOPARTICLES; GRAPHENE; AG; HETEROSTRUCTURE; NANOSTRUCTURES;
D O I
10.1039/c8dt00431e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
To develop solar light-driven photocatalysts with high activity and structural stability, Ag3PO4/POM/GO heterojunction has been successfully prepared by a facile method at room temperature. Ag3PO4/POM/ GO shows remarkably enhanced activity and stability for photocatalytic degradation and H-2 production from water-splitting under simulated solar light. The degradation rate of Ag3PO4/POM/GO is 1.8 times and 1.2 times those of Ag3PO4 and Ag3PO4/POMs, respectively. H-2 production using Ag3PO4/POM/GO is 2.0 times that of Ag3PO4/GO. The enhanced photocatalytic performance of Ag3PO4/POM/GO is attributed to the increased surface area, electronegativity and structure stability. The Z-scheme system of Ag3PO4/POM/GO effectively promotes charge separation, resulting in enhanced photocatalytic performance under simulated solar light.
引用
收藏
页码:6225 / 6232
页数:8
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