Desulfurization and Denitrification Performance of Modified Rice Husk Ash-Carbide Slag Absorbent

被引:10
|
作者
Wang, Yali [1 ]
Han, Xiaoning [1 ]
Chen, Meina [1 ]
Cui, Suping [1 ]
Ma, Xiaoyu [1 ]
Hao, Liwei [2 ]
机构
[1] Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
[2] Beijing Bldg Mat Acad Sci Res, State Key Lab Solid Waste Reuse Bldg Mat, Beijing 100041, Peoples R China
关键词
rice husk ash; carbide slag; hydration; modification; desulfurization and denitrification;
D O I
10.3390/ma14010068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the cement industry, SO2 and NOx are generally removed separately. There are many problems, such as large area, high investment cost, secondary pollution and so on. Desulfurization and denitrification technology have become a frontier research direction in the field of air pollution control. In this paper, rice husk ash and carbide slag were compounded and modified to prepare modified rice husk ash-carbide slag composite absorbent, and its desulfurization and denitrification performance and mechanism were studied. The results showed that the NO conversion and SO2 conversion of the modified rice husk ash-carbide slag composite absorbent increased by 44% and 2%, respectively, at 700 degrees C. Fibrous calcium silicate and calcium silicoaluminate hydrates were formed during the hydration process, which made the specific surface area of the absorbent larger and provided more reactive sites. The hydration process increases the content of oxygen-containing functional groups, decreases the hydroxyl/ether C-O functional groups, and increases the content of carboxyl-COO functional groups are conducive to the denitrification reaction.
引用
收藏
页码:1 / 12
页数:12
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