Study on the pyrolysis of Moroccan oil shale with poly (ethylene terephthalate)

被引:11
作者
Aboulkas, A. [1 ,2 ]
El Harfi, K. [1 ,2 ]
El Bouadili, A. [1 ]
Nadifiyine, M. [2 ]
Benchanaa, M. [2 ]
机构
[1] Univ Sultan Moulay Slimane, Fac Polydisciplinaire Beni Mellal, Lab Interdisciplinaire Rech Sci & Tech, Beni Mellal 23000, Morocco
[2] Univ Cadi Ayyad, Fac Sci Semlalia, Dept Chim, Lab Rech React Mat & Optimisat Proc REMATOP, Marrakech 40001, Morocco
关键词
Kinetics; Oil shale; Poly (ethylene terephthalate); Pyrolysis; THERMAL-DEGRADATION KINETICS; THERMOGRAVIMETRIC ANALYSIS; CO-PYROLYSIS; NONISOTHERMAL PYROLYSIS; PROCESSING CONDITIONS; OLIVE RESIDUE; POLYETHYLENE; DECOMPOSITION; POLYPROPYLENE; MIXTURE;
D O I
10.1007/s10973-009-0064-x
中图分类号
O414.1 [热力学];
学科分类号
摘要
Investigations into the pyrolytic behaviours of oil shale, poly (ethylene terephthalate) (PET) and their mixture have been conducted using a thermogravimetric analyzer. Experiments were carried out dynamically by increasing the temperature from 298 to 1273 K with heating rates of 2 to 100 K/min under a nitrogen atmosphere. Discrepancies between the experimental and calculated TG/DTG profiles were considered as a measurement of the extent of interactions occurring on co-pyrolysis. The maximum degradation temperature of each component in the mixture was higher than those the individual components; thus an increase in thermal stability was expected. The kinetic processing of thermogravimetric data was carried out using Flynn-Wall-Ozawa (FWO) method.
引用
收藏
页码:883 / 890
页数:8
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