Particle size-dependent magnetic properties of γ-Fe2O3 nanoparticles
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作者:
Mukadam, MD
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机构:Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
Mukadam, MD
Yusuf, SM
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Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, IndiaBhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
Yusuf, SM
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Sharma, P
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机构:Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
Sharma, P
Kulshreshtha, SK
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机构:Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
Kulshreshtha, SK
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[1] Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Novel Mat & Struct Chem Div, Bombay 400085, Maharashtra, India
The effect of particle size on the magnetic properties of nano-crystalline powders of gamma-Fe2O3 has been studied, using a DC magnetization technique, as a function of temperature and magnetic field. A superparamagnetic-type blocking process is observed in the ZFC and FC magnetization. Coercivity increases with increasing particle size, while the saturation magnetization decreases with increasing particle size. Such anomalous behaviour can be explained in terms of the redistribution of Fe3+ ions, depending on the particle size. (C) 2003 Elsevier B.V. All rights reserved.
机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
Vasquez-Mansilla, M
Zysler, RD
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Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, ArgentinaComis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
Zysler, RD
Apciprete, C
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
Apciprete, C
Dimitrijewits, MI
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
Dimitrijewits, MI
Saragovi, C
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
Saragovi, C
Greneche, JM
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机构:Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina