Preparation and Characterization of 1,2,3,4-Butane four Carboxylate Transition Metal Complexes

被引:1
|
作者
Zhang, Kanglong [1 ]
Qi, Xiaojin [1 ]
机构
[1] China Univ Min & Technol, Yinchuan Coll, Xuzhou, Jiangsu, Peoples R China
关键词
Transition metal complexes; thermogravimetric analysis; 1,2,3,4-butane four carboxylic acid; IR spectra;
D O I
10.1051/itmconf/20192503005
中图分类号
TP18 [人工智能理论];
学科分类号
081104 ; 0812 ; 0835 ; 1405 ;
摘要
1,2,3,4- butane four carboxylic acidis (Na4C8H6O8) is mainly used to prepare photosensitive materials, medical polymer materials and functional polymer membrane materials.As a permanent finishing agent, 1,2,3,4-butane four carboxylic acid plays an irreplaceable role.In this paper, the preparation of metal complexes by the reaction of 1,2,3,4-butane tetracarboxylic acid tetrasodium salt (Na4C8H6O8) with transition metals is described. The composition and structure of the prepared metal complexes were characterized by infrared spectroscopy, thermogravimetric analysis and elemental analysis. At the same time, through the analysis of thermogravimetric curves, the order of thermal stability of metal complexes is (from large to small): Co2C8H6O8 center dot 2H(2)O > Cd2C8H6O8 center dot 2H(2)O > Mn2C8H6O8 center dot 2H(2)O > Ni2C8H6O8 center dot 2H(2)O > Zn2C8H6O8 center dot 2H(2)O > Zn2C8H6O8 center dot 2H(2)O > Cu2C8H6O8 center dot 2H(2)O.
引用
收藏
页数:4
相关论文
共 50 条
  • [21] PREPARATION AND CHARACTERIZATION OF SOLID COMPLEXES OF 2-FURALDEHYDE THIOSEMICARBAZONE WITH SOME TRANSITION-METAL IONS
    ARAVINDAKSHAN, KK
    NAIR, CGR
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (07): : 684 - 687
  • [22] TRANSITION-METAL PTERIDINE COMPLEXES - PREPARATION AND CHARACTERIZATION OF COBALT(II) PTERIDINES
    BURGMAYER, SJN
    STIEFEL, EI
    INORGANIC CHEMISTRY, 1988, 27 (22) : 4059 - 4065
  • [23] PREPARATION AND CHARACTERIZATION OF TRANSITION METAL COMPLEXES OF SEVERAL 5-SUBSTITUTED TETRAZOLIS
    LABINE, P
    BRUBAKER, CH
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (10): : 3383 - &
  • [24] Preparation, analysis, and characterization of some transition metal complexes-a holistic approach
    Blyth, KM
    Mullings, LR
    Phillips, DN
    Pritchard, D
    van Bronswijk, W
    JOURNAL OF CHEMICAL EDUCATION, 2005, 82 (11) : 1667 - 1670
  • [25] Effect of anions on architectures of transition metal complexes with 1,4-bis (1,2,4-triazol-1-yl)butane
    Li, Xia
    Gu, Ya-Kun
    Deng, Xue-Bin
    Zhao, Kai
    Jin, Lin-Pei
    CRYSTENGCOMM, 2011, 13 (22) : 6665 - 6673
  • [26] The first systematic synthesis of heterobimetallic dithiolene-bridged complexes.: Synthesis and characterization of metal complexes of 4-(1′,2′-ethylenedithiolate)-1,3-dithiole-2-one and dimeric metal complexes of 1,2,3,4-butadienetetrathiolate
    Keefer, CE
    Purrington, ST
    Bereman, RD
    Boyle, PD
    INORGANIC CHEMISTRY, 1999, 38 (23) : 5437 - 5442
  • [27] 4,4′-Bipyridine-butane-1,2,3,4-tetracarboxylic acid (1/1)
    Najafpour, M. Mahdi
    Holynska, Malgorzata
    Lis, Tadeusz
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O985 - U1359
  • [28] CIS,TRANS,CIS-1,2,3,4-TETRAVINYLCYCLOBUTANE AND TRANS,TRANS,TRANS-1,2,3,4-TETRAVINYLCYCLO-BUTANE - PREPARATION AND SOME SPECTROSCOPIC PROPERTIES
    GLEITER, R
    HAIDER, R
    GUBERNATOR, K
    BISCHOF, P
    CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (08): : 2983 - 2993
  • [29] Butane-1,2,3,4-tetracarboxylic acid-4,4′-bipyridine (1/2)
    Zhang, Ning
    Shi, Xue-Min
    Shao, Min
    Li, Ming-Xing
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2016 - U4363
  • [30] TRANSITION-METAL IODATES .1. PREPARATION AND CHARACTERIZATION OF 3D IODATES
    NASSAU, K
    SHIEVER, JW
    PRESCOTT, BE
    JOURNAL OF SOLID STATE CHEMISTRY, 1973, 7 (02) : 186 - 204