Nanocellulose/nanobentonite composite anchored with multi-carboxyl functional groups as an adsorbent for the effective removal of Cobalt(II) from nuclear industry wastewater samples

A novel adsorbent, poly(itaconic acid/methacrylic acid)-grafted-nanocellulose/nanobentonite composite [P(IA/MAA)-g-NC/NB] with multi carboxyl functional groups for the effective removal of Cobalt(II) [Co(II)] from aqueous solutions. The adsorbent was characterized using FTIR, XRD, SEM-EDS, AFM and potentiometric titrations before and after adsorption of Co(II) ions. FTIR spectra revealed that Co(II) adsorption on to the polymer may be due to the involvement of -COOH groups. The surface morphological changes were observed by the SEM images. The pH was optimized as 6.0. An adsorbent dose of 2.0 found to be sufficient for the complete removal of Co(II) from 100 mg/L at room temperature. Pseudo-first order and pseudo-second-order models were tested to describe kinetic data and adsorption of Co(II) follows pseudo-second-order model. The equilibrium attained at 120 min. Isotherm studies were conducted and data were analyzed using Langmuir, Freundlich and Sips isotherm models and best fit was Sips model. Thermodynamic study confirmed endothermic and physical nature of adsorption of the Co(II) onto the adsorbent. Desorption experiments were done with 0.1 M HCl proved that without significant loss in performance adsorbent could be reused for six cycles. The practical efficacy and effectiveness of the adsorbent were tested using nuclear industrial wastewater. A double stage batch adsorption system was designed from the adsorption isotherm data of Co(II) by constructing operating lines. (C) 2016 Elsevier Inc. All rights reserved.