A novel acetone sensor utilizing cataluminescence on layered double oxide

This work developed a facile and effective sensor for the determination of acetone, the diabetic biomarker, which was based on cataluminescence (CTL) emission on the surface of layered double oxide (LDO) that is a layered nanomaterial with easy preparation and environmental friendliness. Under the optimized conditions, the linear range of the CTL intensity versus concentration of acetone was 0.1-16 mM with the detection limit of 0.02 mM (S/N = 3). The relative standard deviation (RSD) for 50 repeated measurements of 1.0 mM acetone was 3.6%. Interestingly, there was no or weak response to seven common volatile organic compounds (VOCs), including ethanol, heptanal, ethyl acetate, methanol, formaldehyde, acetic acid and toluene. Furthermore, the proposed CTL sensor was successfully used for sensing acetone inhuman plasma samples of diabetes patients with a satisfactory recovery. The results demonstrated that the proposed CTL sensor had a promising capability for the sensing of acetone in diabetes diagnosis. The possible CTL mechanism from the oxidation of acetone on the surface of LDO was also discussed. (C) 2014 Elsevier B.V. All rights reserved.