The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide

被引：17

作者：

Lyubimov, Sergey E. ^{[1
]}

Kuchurov, Ilya V. ^{[2
]}

Vasil'ev, Andrei A. ^{[2
]}

Tyutyunov, Andrey A. ^{[1
]}

Kalinin, Valery N. ^{[1
]}

Davankov, Vadim A. ^{[1
]}

Zlotin, Sergei G. ^{[2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 19期

关键词：

Asymmetric allylic alkylation; Palladium; Supercritical carbon dioxide; Carboranyldiamidophosphite; EFFICIENT LIGANDS; HYDROGENATION; CARBORANYLPHOSPHITES; PHOSPHORAMIDITES; SUBSTITUTION; PHOSPHITES;

D O I：

10.1016/j.jorganchem.2009.05.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel P-monodentate ligand based on carboranyl alcohol and (S)-2-(anilinomethyl)pyrrolidine provides high enantioselectivities (ee's up to 95%) in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate. The first example of the Pd-catalysed allylic alkylation in supercritical carbon dioxide is also described. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：3047 / 3049

页数：3

共 12 条

[11] Application of a New Amidophosphite Ligand to Rh-Catalyzed Asymmetric Hydrogenation of β-Dehydroamino Acid Derivatives in Supercritical Carbon Dioxide: Activation Effect of Protic Co-solvents
Lyubimov, Sergey E.
Rastorguev, Eugenie A.
Davankov, Vadim A.
CHIRALITY, 2011, 23 (08) : 624 - 627
[12] A Comparison of (R,R)-Me-DUPHOS and (R,R)-DUPHOS-iPr Ligand in the Pd0-Catalysed Asymmetric Allylic Alkylation Reaction: Stereochemical and Kinetic Considerations (pg 6311, 2009)
Marinho, Vanda Raquel
Prates Ramalho, J. P.
Rodrigues, Ana I.
Burke, Anthony J.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (08) : 1593 - 1593

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