The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide

被引：17
作者：
Lyubimov, Sergey E. [1 ]
Kuchurov, Ilya V. [2 ]
Vasil'ev, Andrei A. [2 ]
Tyutyunov, Andrey A. [1 ]
Kalinin, Valery N. [1 ]
Davankov, Vadim A. [1 ]
Zlotin, Sergei G. [2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 19期
关键词：
Asymmetric allylic alkylation; Palladium; Supercritical carbon dioxide; Carboranyldiamidophosphite; EFFICIENT LIGANDS; HYDROGENATION; CARBORANYLPHOSPHITES; PHOSPHORAMIDITES; SUBSTITUTION; PHOSPHITES;
D O I：
10.1016/j.jorganchem.2009.05.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel P-monodentate ligand based on carboranyl alcohol and (S)-2-(anilinomethyl)pyrrolidine provides high enantioselectivities (ee's up to 95%) in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate. The first example of the Pd-catalysed allylic alkylation in supercritical carbon dioxide is also described. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：3047 / 3049
页数：3
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