Pyrolysis of poly[2,4,6-tri(methylamino)borazine] and its conversion into BN fibers

被引：49

作者：

Bernard, S ^{[1
]}

Cornu, D ^{[1
]}

Miele, P ^{[1
]}

Vincent, H ^{[1
]}

Bouix, J ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, UMR 5615, Lab Multimat & Interfaces, F-69622 Villeurbanne, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 657卷 / 1-2期

关键词：

polyMAB; BN fibers; cross-link; polymer-mineral transition; ceramization; crystallization;

D O I：

10.1016/S0022-328X(02)01543-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pyrolysis process of poly[2,4,6-tri(methylamino)borazinel-based fibers has been studied in detail. The condensation of polymer leads to infusible fibers with a three-dimensional polymeric network from 70 to 400 degreesC. A polymer-mineral transition occurs since 400 to give amorphous hydrogenated fibers at 1000 degreesC. The chemical conversion process is complete at 1400 degreesC and the BN fibers crystallize up to 1800 degreesC. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：91 / 97

页数：7

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