Near-IR absorption spectrum of aromatic excimers

被引：49

作者：

Katoh, R ^{[1
]}

Katoh, E ^{[1
]}

Nakashima, N ^{[1
]}

Yuuki, M ^{[1
]}

Kotani, M ^{[1
]}

机构：

[1] GAKUSHUIN UNIV,FAC SCI,TOKYO 171,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 42期

关键词：

D O I：

10.1021/jp964075u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectrum of excimers in fluid media has been measured with l-methylnaphthalene, anthracene, pyrene, and perylene. In all compounds studied an absorption band characteristic of an excimer has been observed in the near-IR. It is shown that the IR band can be understood by assuming that an excimer is essentially a charge-transfer complex: The near-IR band is to be assigned to a transition from the lowest excimer state to a higher state which has an ion-pair character.

引用

页码：7725 / 7728

页数：4

共 31 条

[1]

ANDERSON RW, 1980, PICOSECOND PHENOMENA, V2, P163

[2]

[Anonymous], ADV PHOTOCHEMISTRY

[3]

[Anonymous], 1970, PHOTOPHYSICS AROMATI

[4] ENERGY OF EXCIMER LUMINESCENCE .I. RECONSIDERATION OF EXCIMER PROCESSES [J].