Characterization of photocatalytic performance of silver deposited TiO2 nanorods

被引:41
作者
Yun, Hyeong Jin [1 ]
Lee, Hyunjoo [2 ]
Kim, Nam Dong [1 ]
Yi, Jongheop [1 ]
机构
[1] Seoul Natl Univ, Sch Chem & Bioengn, Seoul 443749, South Korea
[2] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
Photocatalyst; Silver deposited TiO2; Surface modification; Shape effect; Photocatalytic decomposition; SENSITIZED SOLAR-CELLS; NANOPARTICLES; DEGRADATION; WATER;
D O I
10.1016/j.elecom.2008.11.044
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ag-TiO2 nanorods were synthesized via gel-sol methods. Cyclic voltammetry results showed that surface modification of TiO2 nanorods using Ag led better electrochemical activity involving fast electron transfer to electrode. Electrochemical impedance spectroscopy results revealed that the increase in aspect ratio of TiO2 nanorods and surface modification resulted in synergetic effect of reduction of e(-)/h(+) recombination and charge transfer resistance. Consequently the use of Ag-TiO2 nanorods as photocatalysts exhibited significant increase in photocatalytic decomposition rate of acid red 44. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:363 / 366
页数:4
相关论文
共 15 条
[1]   Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like TiO2 nanowires made by the "oriented attachment" mechanism [J].
Adachi, M ;
Murata, Y ;
Takao, J ;
Jiu, JT ;
Sakamoto, M ;
Wang, FM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) :14943-14949
[2]  
Barsoukov E, 2005, IMPEDANCE SPECTROSCOPY: THEORY, EXPERIMENT, AND APPLICATIONS, 2ND EDITION, pXII
[3]   Photocatalytic degradation of cyanide using titanium dioxide modified with copper oxide [J].
Chiang, K ;
Amal, R ;
Tran, T .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (04) :471-485
[4]   Low-temperature synthesis of soluble and processable organic-capped anatase TiO2 nanorods [J].
Cozzoli, PD ;
Kornowski, A ;
Weller, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) :14539-14548
[5]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[6]   Nanorod-based dye-sensitized solar cells with improved charge collection efficiency [J].
Kang, Soon Hyung ;
Choi, Sang-Hyun ;
Kang, Moon-Sung ;
Kim, Jae-Yup ;
Kim, Hyun-Sik ;
Hyeon, Taeghwan ;
Sung, Yung-Eun .
ADVANCED MATERIALS, 2008, 20 (01) :54-+
[7]   Highly ordered TiO2 nanotube arrays with controllable length for photoelectrocatalytic degradation of phenol [J].
Liu, Zhaoyue ;
Zhang, Xintong ;
Nishimoto, Shunsuke ;
Jin, Ming ;
Tryk, Donald A. ;
Murakami, Taketoshi ;
Fujishima, Akira .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (01) :253-259
[8]   Semiconducting properties of self-organized TiO2 nanotubes [J].
Munoz, A. G. .
ELECTROCHIMICA ACTA, 2007, 52 (12) :4167-4176
[9]   A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].
OREGAN, B ;
GRATZEL, M .
NATURE, 1991, 353 (6346) :737-740
[10]   Effect of deposition of Ag on TiO2 nanoparticles on the photodegradation of Reactive Yellow-17 [J].
Rupa, A. Valentine ;
Manikandan, D. ;
Divakar, D. ;
Sivakumar, T. .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 147 (03) :906-913