Lithium heptadecafluorooctanesulfate and aza-Diels-Alder reactions in catalyzed Mannich-type supercritical carbon dioxide

被引：21
作者：
Shi, M [1 ]
Cui, SC [1 ]
Li, QH [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Organomet Chem, Shanghai 200032, Peoples R China
来源：
TETRAHEDRON | 2004年 / 60卷 / 29期
基金：
中国国家自然科学基金;
关键词：
Mannich-type reaction; aza-Diels-Alder reaction; imines; (1-methoxy-2-methylpropenyloxy)trimethylsilane; Danishefsky's diene; supercritical carbon dioxide; lithium heptadecafluorooctanesulfonate; environmentally benign conditions;
D O I：
10.1016/j.tet.2004.05.065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Mannich-type reaction of imines with (1-methoxy-2-methylpropenyloxy)trimethylsilane and aza-Diels-Alder reaction of imines with Danishefsky's diene can be carried out in scCO(2) in the presence of lithium heptadecafluorooctanesulfonate which offer a way to synthesize beta-amino carbonyl compounds and nitrogen-containing six-membered ring compounds under environmentally benign conditions. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6163 / 6167
页数：5
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