Technological Aspects of Chemoenzymatic Epoxidation of Fatty Acids, Fatty Acid Esters and Vegetable Oils: A Review

被引:63
作者
Milchert, Eugeniusz [1 ]
Malarczyk, Kornelia [1 ]
Klos, Marlena [1 ]
机构
[1] West Pomeranian Univ Technol, Inst Organ Chem Technol, Fac Chem Engn, PL-70322 Szczecin, Poland
关键词
fatty acids; alkyl fatty acid esters; free fatty acids; epoxidation; EPOXIDIZED SOYBEAN OIL; LIPASE-CATALYZED SYNTHESIS; PONGAMIA-GLABRA OIL; HYDROGEN-PEROXIDE; ENZYMATIC-SYNTHESIS; METHYL OLEATE; OLEIC-ACID; SEED OIL; RUBBER; STABILITY;
D O I
10.3390/molecules201219778
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The general subject of the review is analysis of the effect of technological parameters on the chemoenzymatic epoxidation processes of vegetable oils, fatty acids and alkyl esters of fatty acids. The technological parameters considered include temperature, concentration, amount of hydrogen peroxide relative to the number of unsaturated bonds, the amounts of enzyme catalysts, presence of solvent and amount of free fatty acids. Also chemical reactions accompanying the technological processes are discussed together with different technological options and significance of the products obtained.
引用
收藏
页码:21481 / 21493
页数:13
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