Technological Aspects of Chemoenzymatic Epoxidation of Fatty Acids, Fatty Acid Esters and Vegetable Oils: A Review

被引：63
作者：
Milchert, Eugeniusz [1 ]
Malarczyk, Kornelia [1 ]
Klos, Marlena [1 ]
机构：
[1] West Pomeranian Univ Technol, Inst Organ Chem Technol, Fac Chem Engn, PL-70322 Szczecin, Poland
来源：
MOLECULES | 2015年 / 20卷 / 12期
关键词：
fatty acids; alkyl fatty acid esters; free fatty acids; epoxidation; EPOXIDIZED SOYBEAN OIL; LIPASE-CATALYZED SYNTHESIS; PONGAMIA-GLABRA OIL; HYDROGEN-PEROXIDE; ENZYMATIC-SYNTHESIS; METHYL OLEATE; OLEIC-ACID; SEED OIL; RUBBER; STABILITY;
D O I：
10.3390/molecules201219778
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The general subject of the review is analysis of the effect of technological parameters on the chemoenzymatic epoxidation processes of vegetable oils, fatty acids and alkyl esters of fatty acids. The technological parameters considered include temperature, concentration, amount of hydrogen peroxide relative to the number of unsaturated bonds, the amounts of enzyme catalysts, presence of solvent and amount of free fatty acids. Also chemical reactions accompanying the technological processes are discussed together with different technological options and significance of the products obtained.
引用
收藏
页码：21481 / 21493
页数：13
相关论文
共 87 条
[1]  
Abdullah Bashar Mudhaffar, 2010, Journal of Applied Sciences, V10, P1545, DOI 10.3923/jas.2010.1545.1553
[2]   Epoxidized soybean oil as a potential source of high-temperature lubricants [J].
Adhvaryu, A ;
Erhan, SZ .
INDUSTRIAL CROPS AND PRODUCTS, 2002, 15 (03) :247-254
[3]   The use of lipases as biocatalysts for the epoxidation of fatty acids and phenolic compounds [J].
Aouf, Chahinez ;
Durand, Erwann ;
Lecomte, Jerome ;
Figueroa-Espinoza, Maria-Cruz ;
Dubreucq, Eric ;
Fulcrand, Helene ;
Villeneuve, Pierre .
GREEN CHEMISTRY, 2014, 16 (04) :1740-1754
[4]   Kinetics of tungsten-catalyzed sunflower oil epoxidation studied by 1H NMR [J].
Benaniba, Mohamed Tahar ;
Belhaneche-Bensemra, Naima ;
Gellbard, Georges .
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2007, 109 (12) :1186-1193
[5]  
Biermann U, 2000, ANGEW CHEM INT EDIT, V39, P2206, DOI 10.1002/1521-3773(20000703)39:13<2206::AID-ANIE2206>3.0.CO
[6]  
2-P
[7]   Synthesis of diethylamine-functionalized soybean oil [J].
Biswas, A ;
Adhvaryu, A ;
Gordon, SH ;
Erhan, SZ ;
Willett, JL .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2005, 53 (24) :9485-9490
[8]   LIPASE CATALYZED SYNTHESIS OF PEROXYCARBOXYLIC ACIDS AND LIPASE MEDIATED OXIDATIONS [J].
BJORKLING, F ;
FRYKMAN, H ;
GODTFREDSEN, SE ;
KIRK, O .
TETRAHEDRON, 1992, 48 (22) :4587-4592
[9]   LIPASE-MEDIATED FORMATION OF PEROXYCARBOXYLIC ACIDS USED IN CATALYTIC EPOXIDATION OF ALKENES [J].
BJORKLING, F ;
GODTFREDSEN, SE ;
KIRK, O .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (19) :1301-1303
[10]   Chemical and rheological characterizations of some vegetable oils derivatives commonly used in printing inks [J].
Blayo, A ;
Gandini, A ;
Le Nest, JF .
INDUSTRIAL CROPS AND PRODUCTS, 2001, 14 (02) :155-167
123456789