Organic-Inorganic Hybrid Polymers as Adsorbents for Removal of Heavy Metal Ions from Solutions: A Review

被引:280
作者
Samiey, Babak [1 ]
Cheng, Chil-Hung [2 ]
Wu, Jiangning [2 ]
机构
[1] Lorestan Univ, Dept Chem, Fac Sci, Khorramabad 6813717133, Iran
[2] Ryerson Univ, Dept Chem Engn, Toronto, ON M5B 2K3, Canada
关键词
organic-inorganic hybrid polymer; heavy metal ion; wastewater treatment; adsorption; sol-gel method; self-assembly process; nanobuilding blocks; interpenetrating networks; FUNCTIONALIZED MESOPOROUS SILICA; WASTE-WATER TREATMENT; AQUEOUS-SOLUTION; ADSORPTION PROPERTIES; MOLECULAR-SIEVES; HIGH-CAPACITY; MAGNETIC NANOPARTICLES; HEXAVALENT CHROMIUM; SELECTIVE ADSORBENT; HYDROGEL COMPOSITE;
D O I
10.3390/ma7020673
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Over the past decades, organic-inorganic hybrid polymers have been applied in different fields, including the adsorption of pollutants from wastewater and solid-state separations. In this review, firstly, these compounds are classified. These compounds are prepared by sol-gel method, self-assembly process (mesopores), assembling of nanobuilding blocks (e. g., layered or core-shell compounds) and as interpenetrating networks and hierarchically structures. Lastly, the adsorption characteristics of heavy metals of these materials, including different kinds of functional groups, selectivity of them for heavy metals, effect of pH and synthesis conditions on adsorption capacity, are studied.
引用
收藏
页码:673 / 726
页数:54
相关论文
共 257 条
[1]   Transition metal-containing macromolecules: En route to new functional materials [J].
Abd-El-Aziz, Alaa S. ;
Strohm, Elizabeth A. .
POLYMER, 2012, 53 (22) :4879-4921
[2]   Adsorption of aqueous mercury(II) on propylthiol-functionalized mesoporous silica obtained by cocondensation [J].
Aguado, J ;
Arsuaga, JM ;
Arencibia, A .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (10) :3665-3671
[3]   Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica [J].
Aguado, Jose ;
Arsuaga, Jesus M. ;
Arencibia, Amaya ;
Lindo, Montana ;
Gascon, Victoria .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 163 (01) :213-221
[4]   Synthesis, characterization and study of the chromogenic properties of the hybrid polyoxometalates [PW11O39(SiR)2O]3-(R = Et, (CH2)nCH=CH2 (n = 0, 1, 4), CH2CH2SiEt3, CH2CH2SiMe2Ph) [J].
Agustin, Dominique ;
Dallery, Jerome ;
Coelho, Cristina ;
Proust, Anna ;
Thouvenot, Rene .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (04) :746-754
[5]   Polymer-layered silicate nanocomposites: Preparation, properties and uses of a new class of materials [J].
Alexandre, Michael ;
Dubois, Philippe .
Materials Science and Engineering: R: Reports, 2000, 28 (1-2) :1-63
[6]  
Andreyev M.K., 2012, ZEOLITES SYNTHESIS C
[7]   Synthesis and characterization of carboxyl terminated poly(methacrylic acid) grafted chitosan/bentonite composite and its application for the recovery of uranium(VI) from aqueous media [J].
Anirudhan, T. S. ;
Rijith, S. .
JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2012, 106 :8-19
[8]   Heavy metals uptake from aqueous solutions and industrial wastewaters by humic acid-immobilized polymer/bentonite composite: Kinetics and equilibrium modeling [J].
Anirudhan, T. S. ;
Suchithra, P. S. .
CHEMICAL ENGINEERING JOURNAL, 2010, 156 (01) :146-156
[9]  
[Anonymous], 1985, SOIL CHEM
[10]   Benzoylthiourea-modified mesoporous silica for mercury(II) removal [J].
Antochshuk, V ;
Olkhovyk, O ;
Jaroniec, M ;
Park, IS ;
Ryoo, R .
LANGMUIR, 2003, 19 (07) :3031-3034