(S)-[2-(1-aminoethyl)phenyl]chloro(3-chloropyridine)palladium(II) acetone 0.25-solvate

被引：2
|
作者：
Calmuschi-Cula, Beatrice
Timofte, Claudia
Englert, Ulli
机构：
[1] Univ Aachen, Inst Inorgan Chem, Rhein Westfal TH Aachen, D-52074 Aachen, Germany
[2] Univ Bucharest, Dept Mat, Fac Phys, RO-077125 Bucharest, Romania
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S160053680603902X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title crystal structure, [Pd(C8H10N)Cl(C5H4ClN)]center dot 0.25C(3)H(6)O, has four independent complex molecules, and half each of two acetone molecules, the solvent molecules being located on twofold axes, in the asymmetric unit. The angle subtended by the pyridine ring and the mean plane formed by the Pd atom and its directly bonded atoms in each of the four molecules varies over a range of 14 degrees. This conformational flexibility may well reflect the influence of crystal packing on the molecular structure.
引用
收藏
页码：M2791 / M2793
页数：3
相关论文
共 50 条
  • [1] (R)-Di-μ-acetato-κ2 O:O′-bis{[2-(1-aminoethyl)phenyl-κ2C1,N]palladium(II)}, (R)-di-μ-chloro-bis{[2-(1-aminoethyl)phenyl-κ2 C1,N]palladium(II)} and [SP-4-4]-(R)[2-(1-aminoethyl)phenyl-κ2C1,N]chloro(pyridine-κN)palladium(II)
    Calmuschi, B
    Englert, U
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2002, 58 (11) : m545 - m548
  • [2] (S)-(acetylacetonato-κ2O,O′)[2-(1-aminoethyl)phenyl-κ2C1,N]palladium(II)
    Calmuschi, B
    Englert, U
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M164 - M165
  • [3] (S)-[2-(1-aminoethyl)phenyl-κ2C1,N](hexafluoroacetylacetonato-κ2O,O′)palladium(II)
    Calmuschi, B
    Englert, U
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M166 - M167
  • [4] Enzymatic resolution of (RS)-2-(1-aminoethyl)-3-chloro-5-(substituted)pyridines
    Sigmund, AE
    DiCosimo, R
    TETRAHEDRON-ASYMMETRY, 2004, 15 (18) : 2797 - 2799
  • [5] rac-[2-(1-aminoethyl)phenyl-κ2C1,N](hexafluoroacetylacetonato-κ2O,O′)palladium(II)
    Calmuschi, B
    Englert, U
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M168 - M170
  • [6] 1-(2-(2-(2-(1-Aminoethyl)phenyl)diselanyl)phenyl)ethanamine: An amino organoselenium compound with interesting antioxidant profile
    Ibrahim, Mohammad
    Hassan, Waseem
    Anwar, Javed
    Deobald, Anna Maria
    Kamdem, Jean Paul
    Souza, Diogo Onofre
    Teixeira Rocha, Joao Batista
    TOXICOLOGY IN VITRO, 2014, 28 (04) : 524 - 530
  • [7] Synthesis of (S)-5-(1-aminoethyl)-2-(cyclohexylmethoxy)benzamide
    Luke, GP
    Holt, DA
    TETRAHEDRON-ASYMMETRY, 1999, 10 (22) : 4393 - 4403
  • [8] [2-(isopropylthio)benzoato-O,S]-phenyl(triphenylphosphine)palladium(II) tetrahydrofuran solvate
    Thompson, C
    Kruger, GJ
    Meyer, WH
    Brüll, R
    Raubenheimer, HG
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : 332 - 333
  • [9] [rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N')palladium(II) 3-methylbenzoate monohydrate
    Serb, Mihaela-Diana
    Kalf, Irmgard
    Englert, Ulli
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M976 - U1076
  • [10] [rac-2-(1-Aminoethyl)phenyl-κ2 C 1,N](ethylendiamine-κ2 N,N')palladium(II) 3,5-dimethylbenzoate
    Serb, Mihaela-Diana
    Kalf, Irmgard
    Englert, Ulli
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M977 - U1088
12345