High performance In2(MoO4)3@In2O3 nanocomposites gas sensor with long-term stability

被引:34
作者
Zhang, Feng-Hua [1 ,2 ]
Wang, Yu-Chong [1 ]
Wang, Lei [3 ]
Liu, Jian [4 ]
Ge, Hong-Liang [5 ]
Wang, Bin [1 ]
Huang, Xin-Yu [1 ]
Wang, Xue-Dong [6 ]
Chi, Zong-Tao [1 ]
Xie, Wan-Feng [1 ,2 ,5 ]
机构
[1] Qingdao Univ, Sch Elect & Informat Engn, Qingdao 266071, Shandong, Peoples R China
[2] Shandong Univ, Sch Phys, Jinan 250100, Shandong, Peoples R China
[3] Shandong Earthquake Agcy, Key Lab Engn Earthquake, Jinan 250102, Shandong, Peoples R China
[4] Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China
[5] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China
[6] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal oxide semiconductor; In-2(MoO4)(3); Sensing; Hydrothermal; Humidity; ETHANOL SENSING PROPERTIES; ZNO NANORODS; TEMPERATURE; SENSITIVITY; SELECTIVITY; MOLYBDENUM; PHASE;
D O I
10.1016/j.jallcom.2019.06.369
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal oxide semiconductor (MOSC) sensors based on nanocrystalline MoO3, In2O3, and their composites are considered to be very sensitive to detect low concentrations of ethanol, ozone, hydrogen, formaldehyde, and nitrogen dioxide. Here, we firstly introduced In-2(MoO4)(3) phase, which has excellent negative thermal expansion and high electric conductivity properties, into In-2(MoO4)(3)@In2O3 crystalline nanocomposites. The gas-sensing performance of the In-2 (MoO4)(3)@In2O3 nanocomposites was studied upon exposure to the ethanol gas with different concentration from 5 to 300 ppm at the optimum temperature (300 degrees C). What's more, the device possesses ultra-high response of 110 and selectivity to ethanol. Particularly, it can effectively work in high humidity (RH = 80%) with super long-term stability of as long as 90 days, compared with the pristine In2O3 sensor and previous reports. The presented novel In-2(MoO4)(3)@In2O3 sensor offers great opportunities for future ethanol detection under harsh conditions. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:180 / 188
页数:9
相关论文
共 39 条
  • [11] Non plasmonic semiconductor quantum SERS probe as a pathway for in vitro cancer detection
    Haldavnekar, Rupa
    Venkatakrishnan, Krishnan
    Tan, Bo
    [J]. NATURE COMMUNICATIONS, 2018, 9
  • [12] Rational interaction between the aimed gas and oxide surfaces enabling high-performance sensor: The case of acidic α-MoO3 nanorods for selective detection of triethylamine
    He, Saihuan
    Li, Wending
    Feng, Liang
    Yang, Wei
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 783 : 574 - 582
  • [13] High Mobility Indium Oxide Electron Transport Layer for an Efficient Charge Extraction and Optimized Nanomorphology in Organic Photovoltaics
    Huang, Wenchao
    Zhu, Bowen
    Chang, Sheng-Yung
    Zhu, Shuan Lin
    Cheng, Pei
    Hsieh, Yao-Tsung
    Meng, Lei
    Wang, Rui
    Wang, Chaochen
    Zhu, Chenhui
    McNeill, Christopher
    Wang, Mingkui
    Yang, Yang
    [J]. NANO LETTERS, 2018, 18 (09) : 5805 - 5811
  • [14] SnO2 functionalized AlGaN/GaN high electron mobility transistor for hydrogen sensing applications
    Hung, Shao-Tsu
    Chang, Chi-Jung
    Hsu, Chien-Hsing
    Chu, Byung Hwan
    Lo, Chien Fong
    Hsu, Chin-Ching
    Pearton, Stephen J.
    Holzworth, Monta Raymond
    Whiting, Patrick Guzek
    Rudawski, Nicholas Guy
    Jones, Kevin S.
    Dabiran, Amir
    Chow, Peter
    Ren, Fan
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (18) : 13783 - 13788
  • [15] 3D-multilayer MoS2 nanosheets vertically grown on highly mesoporous cubic In2O3 for high-performance gas sensing at room temperatur
    Ikram, Muhammad
    Liu, Yang
    Lv, He
    Liu, Lujia
    Rehman, Afrasiab Ur
    Kan, Kan
    Zhang, WeiJun
    He, Lang
    Wang, Yang
    Wang, Ruihong
    Shi, Keying
    [J]. APPLIED SURFACE SCIENCE, 2019, 466 : 1 - 11
  • [16] Hydrogen and ethanol sensing properties of molybdenum oxide nanorods based thin films: Effect of electrode metallization and humid ambience
    Illyaskutty, Navas
    Kohler, Heinz
    Trautmann, Thomas
    Schwotzer, Matthias
    Pillai, V. P. Mahadevan
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2013, 187 : 611 - 621
  • [17] Chitosan-templated Pt nanocatalyst loaded mesoporous SnO2 nanofibers: a superior chemiresistor toward acetone molecules
    Jeong, Yong Jin
    Koo, Won-Tae
    Jang, Ji-Soo
    Kim, Dong-Ha
    Cho, Hee-Jin
    Kim, Il-Doo
    [J]. NANOSCALE, 2018, 10 (28) : 13713 - 13721
  • [18] 2D-MoO3 nanosheets for superior gas sensors
    Ji, Fangxu
    Ren, Xianpei
    Zheng, Xiaoyao
    Liu, Yucheng
    Pang, Liuqing
    Jiang, Jiaxing
    Liu, Shengzhong
    [J]. NANOSCALE, 2016, 8 (16) : 8696 - 8703
  • [19] Modulation-Doped In2O3/ZnO Heterojunction Transistors Processed from Solution
    Khim, Dongyoon
    Lin, Yen-Hung
    Nam, Sungho
    Faber, Hendrik
    Tetzner, Kornelius
    Li, Ruipeng
    Zhang, Qiang
    Li, Jun
    Zhang, Xixiang
    Anthopoulos, Thomas D.
    [J]. ADVANCED MATERIALS, 2017, 29 (19)
  • [20] Hierarchical Porous Nanosheets Constructed by Graphene-Coated, Interconnected TiO2 Nanoparticles for Ultrafast Sodium Storage
    Li, Baosong
    Xi, Baojuan
    Feng, Zhenyu
    Lin, Yue
    Liu, Jincheng
    Feng, Jinkui
    Qian, Yitai
    Xiong, Shenglin
    [J]. ADVANCED MATERIALS, 2018, 30 (10)