Synthesis and characterization of new palladium complexes based on polydentate chiral Schiff base and amines ligands derived from (+)-2-hydroxypinan-3-one

被引：5
作者：
Gur'eva, Yana A. [1 ]
Alekseev, Igor N. [1 ]
Dvornikova, Irina A. [1 ]
Zalevskaya, Olga A. [2 ]
Kuchin, Aleksandr V. [1 ]
机构：
[1] Russian Acad Sci, Ural Branch, Komi Sci Ctr, Inst Chem, 48 Pervomaiskaya St, Moscow 167000, Russia
[2] Syktyvkar State Univ, 55 Oktyabrsky Ave, Syktyvkar 167001, Russia
来源：
INORGANICA CHIMICA ACTA | 2018年 / 477卷
基金：
俄罗斯基础研究基金会;
关键词：
Palladium complexes; Chiral pinane ligands; Diimines; Diamines; Ligands of salen type; chelate complexes; NMR; BOND-FORMING REACTIONS; PINCER COMPLEXES; ELECTROCHEMICAL PROPERTIES; PLATINUM(II) COMPLEXES; MOLECULAR DOCKING; ALPHA-PINENE; C-C; CATALYSTS; PALLADACYCLES; ETHYLENEDIAMINE;
D O I：
10.1016/j.ica.2018.03.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Seven novel palladium complexes of the type [Pd(HL)Cl-2] and [Pd(L)Cl] containing chiral pinane ligands (HL = 3-[(2-aminoethyl)imino]-pinane-2-ol; 3,3'-(ethylenediimino)bis-pinane-2-ol; cis-3-(2-aminoethylamino)-pinane-2-ol; cis-3,3'(ethylenediamino)bis-pinane-2-ol; trans-3,3'(ethylenediamino)bis-pinane-2-ol; 3-[2-(2-hydroxybenzylamino)ethylamino]-pinane-2-ol; L = 3-[2-(3,5-di-tert-butyl-2-hydroxybenzylidene)aminoethylimino]pinane-2-ol) were synthesized in good yields from the direct reaction of chiral nitrogen ligands with Li2PdCl4 in MeOH. These synthesized complexes were characterized by means of elemental analysis, FT-IR, multidimensional and multinuclear NMR spectroscopic methods. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：300 / 305
页数：6
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