The Construction of the Heterostructural Bi2O3/g-C3N4 Composites with an Enhanced Photocatalytic Activity

被引:17
作者
Zhang, Jinhua [1 ]
Qian, Huiyue [1 ]
Liu, Wencheng [1 ]
Chen, Hao [1 ]
Qu, Yang [1 ]
Lin, Zhidong [2 ]
机构
[1] Huazhong Agr Univ, Dept Chem, Coll Sci, Wuhan 430070, Hubei, Peoples R China
[2] Wuhan Inst Technol, Hubei Key Lab Plasma Chem & Adv Mat, Wuhan 430073, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
g-C3N4; Bi2O3; heterostructural composite; photocatalytic activity; VISIBLE-LIGHT; HIGH-PERFORMANCE; Z-SCHEME; HYDROGEN; HETEROJUNCTIONS; DEGRADATION; FABRICATION; NANOPARTICLES; NANOSHEETS; SNO2;
D O I
10.1142/S1793292018500637
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A heterostructural composite composed of g-C3N4 and Bi2O3 was achieved by the one-pot and thermal-induced polycondensation method using melamine and Bi(NO3)(3) as precursor at 550 degrees C under air atmosphere. The crystalline phase, components and morphologies of the as-prepared composites were investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Besides, the photocatalytic activity of composites was evaluated by degrading RhB aqueous solution at room temperature under visible light irradiation. Compared with bulk g-C3N4, the photocatalytic efficiency of the 0.5% Bi2O3/g-C3N4 (Bi-CN) was increased by up to four times. The introduction of Bi2O3 enhances not only the light absorption ability, but also the separation of photogenerated electron-hole pairs.
引用
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页数:9
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共 35 条
[1]   Novel Mesoporous Graphite Carbon Nitride/BiOI Heterojunction for Enhancing Photocatalytic Performance Under Visible-Light Irradiation [J].
Chang, Chun ;
Zhu, Lingyan ;
Wang, Shanfeng ;
Chu, Xiaolong ;
Yue, Longfei .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (07) :5083-5093
[2]   Enhanced photocatalytic performance of g-C3N4/Bi4Ti3O12 heterojunction nanocomposites [J].
Cui, Ziming ;
Yang, Hua ;
Zhao, Xinxin .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2018, 229 :160-172
[3]   An Advanced Semimetal-Organic Bi Spheres-g-C3N4 Nanohybrid with SPR-Enhanced Visible-Light Photocatalytic Performance for NO Purification [J].
Dong, Fan ;
Zhao, Zaiwang ;
Sun, Yanjuan ;
Zhang, Yuxin ;
Yan, Shuai ;
Wu, Zhongbiao .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2015, 49 (20) :12432-12440
[4]   Facile transformation of low cost thiourea into nitrogen-rich graphitic carbon nitride nanocatalyst with high visible light photocatalytic performance [J].
Dong, Fan ;
Sun, Yanjuan ;
Wu, Liwen ;
Fu, Min ;
Wu, Zhongbiao .
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (07) :1332-1335
[5]   High performance, recoverable Fe3O4-ZnO nanoparticles for enhanced photocatalytic degradation of phenol [J].
Feng, Xiaohui ;
Guo, Haijuan ;
Patel, Kunal ;
Zhou, Hong ;
Lou, Xia .
CHEMICAL ENGINEERING JOURNAL, 2014, 244 :327-334
[6]   Facile synthesis of new, highly efficient SnO2/carbon nitride composite photocatalysts for the hydrogen evolution reaction [J].
Fettkenhauer, Ch. ;
Clavel, G. ;
Kailasam, K. ;
Antoniettia, M. ;
Dontsova, D. .
GREEN CHEMISTRY, 2015, 17 (06) :3350-3361
[7]   Room-temperature in situ fabrication of Bi2O3/g-C3N4 direct Z-scheme photocatalyst with enhanced photocatalytic activity [J].
He, Rongan ;
Zhou, Jiaqian ;
Fu, Huiqing ;
Zhang, Shiying ;
Jiang, Chuanjia .
APPLIED SURFACE SCIENCE, 2018, 430 :273-282
[8]   Variational analysis for angle-ply laminates with matrix cracks [J].
Huang, Z. Q. ;
Zhou, J. C. ;
He, X. Q. ;
Liew, K. M. .
INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES, 2014, 51 (21-22) :3669-3678
[9]   Facile assembly of Bi2O3/Bi2S3/MoS2 n-p heterojunction with layered n-Bi2O3 and p-MoS2 for enhanced photocatalytic water oxidation and pollutant degradation [J].
Ke, Jun ;
Liu, Jie ;
Sun, Hongqi ;
Zhang, Huayang ;
Duan, Xiaoguang ;
Liang, Ping ;
Li, Xinyong ;
Tade, Moses O. ;
Liu, Shaomin ;
Wang, Shaobin .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 200 :47-55
[10]   Production of electricity and hydrogen by photocatalytic degradation of organic wastes in a photoelectrochemical cell The concept of the Photofuelcell: A review of a re-emerging research field [J].
Lianos, Panagiotis .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 185 (2-3) :575-590