Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

被引：32

作者：

Amaya, Toru ^{[1
]}

Takahashi, Yuki ^{[1
]}

Moriuchi, Toshiyuki ^{[1
]}

Hirao, Toshikazu ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 36期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

TRANSITION-METAL-COMPLEXES; CORANNULENE TETRAANION; FLUORENYL COMPLEXES; COORDINATION; BUCKYBOWL; ZIRCONIUM; HYDROCARBON; CATALYSTS; NANOBELT; IRIDIUM;

D O I：

10.1021/ja5072459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono- and trinuclear sumanenyl zirconocene complexes Cp(sumanenyl)ZrCl2, Cp*(sumanenyl)ZrCl2, and (C21H9)[(Cp*)ZrCl2](3) were successfully synthesized. In the mononuclear complexes, convex binding with disturbed eta(5)-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes.

引用

页码：12794 / 12798

页数：5

共 48 条

[41] Geodesic polyarenes by flash vacuum pyrolysis [J].

Tsefrikas, Vikki M. ;

Scott, Lawrence T. .

CHEMICAL REVIEWS, 2006, 106 (12) :4868-4884

[42] Synthesis and structure of a dimetallated buckybowl:: Coordination of one {Cp*Ru}+ unit to each side of corannulene [J].

Vecchi, PA ;

Alvarez, CM ;

Ellern, A ;

Angelici, RJ ;

Sygula, A ;

Sygula, R ;

Rabideau, PW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (34) :4497-4500

[43] Flattening of a curved-surface buckybowl (corannulene) by η6 coordination to {Cp*Ru}+ [J].

Vecchi, PA ;

Alvarez, CM ;

Ellern, A ;

Angelici, RJ ;

Sygula, A ;

Sygula, R ;

Rabideau, PW .

ORGANOMETALLICS, 2005, 24 (19) :4543-4552

[44] Aromatic molecular-bowl hydrocarbons: Synthetic derivatives, their structures, and physical properties [J].

Wu, Yao-Ting ;

Siegel, Jay S. .

CHEMICAL REVIEWS, 2006, 106 (12) :4843-4867

[45] Tightening of the Nanobelt upon Multielectron Reduction [J].

Zabula, Alexander V. ;

Filatov, Alexander S. ;

Xia, Jianlong ;

Jasti, Ramesh ;

Petrukhina, Marina A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (19) :5033-5036

[46] Pentadecker Supramolecules with a Lithium Alkoxo Nanobelt Sandwiched between Two Highly Charged Buckybowl Surfaces [J].

Zabula, Alexander V. ;

Spisak, Sarah N. ;

Filatov, Alexander S. ;

Petrukhina, Marina A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (49) :12194-12198

[47] A Main Group Metal Sandwich: Five Lithium Cations Jammed Between Two Corannulene Tetraanion Decks [J].

Zabula, Alexander V. ;

Filatov, Alexander S. ;

Spisak, Sarah N. ;

Rogachev, Andrey Yu. ;

Petrukhina, Marina A. .

SCIENCE, 2011, 333 (6045) :1008-1011

[48] The electrochemical inspection of the redox activity of sumanene and its concave CpFe complex [J].

Zanello, Piero ;

Fedi, Serena ;

de Biani, Fabrizia Fabrizi ;

Giorgi, Gianluca ;

Amaya, Toru ;

Sakane, Hiroyuki ;

Hirao, Toshikazu .

DALTON TRANSACTIONS, 2009, (42) :9192-9197

← 1 2 3 4 5 →