Sumanenyl Metallocenes: Synthesis and Structure of Mono- and Trinuclear Zirconocene Complexes

被引：32

作者：

Amaya, Toru ^{[1
]}

Takahashi, Yuki ^{[1
]}

Moriuchi, Toshiyuki ^{[1
]}

Hirao, Toshikazu ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 36期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

TRANSITION-METAL-COMPLEXES; CORANNULENE TETRAANION; FLUORENYL COMPLEXES; COORDINATION; BUCKYBOWL; ZIRCONIUM; HYDROCARBON; CATALYSTS; NANOBELT; IRIDIUM;

D O I：

10.1021/ja5072459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mono- and trinuclear sumanenyl zirconocene complexes Cp(sumanenyl)ZrCl2, Cp*(sumanenyl)ZrCl2, and (C21H9)[(Cp*)ZrCl2](3) were successfully synthesized. In the mononuclear complexes, convex binding with disturbed eta(5)-bonding was confirmed in a solid state. As demonstrated in the trinuclear complex, the multibenzylic anion of sumanene offers a novel ligand for the multinuclear metallocenes.

引用

页码：12794 / 12798

页数：5

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