Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks

被引:10
作者
Makiura, Rie [1 ,2 ]
Usui, Ryo [1 ,3 ]
Pohl, Ehmke [4 ]
Prassides, Kosmas [4 ,5 ]
机构
[1] Osaka Prefecture Univ, Nanosci & Nanotechnol Res Ctr, Res Org 21st Century, Sakai, Osaka 5998570, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
[3] Osaka Prefecture Univ, Grad Sch Engn, Dept Phys & Elect, Naka Ku, Sakai, Osaka 5998531, Japan
[4] Univ Durham, Dept Chem, Durham DH1 3LE, England
[5] Tohoku Univ, WPI Res Ctr, AIMR, Sendai, Miyagi 9808577, Japan
关键词
METAL-ORGANIC FRAMEWORK; BUILDING-BLOCKS; SHEETS; NANOSHEETS; NANOSTRUCTURES; ARCHITECTURES; FABRICATION; SURFACES; SOLIDS; GROWTH;
D O I
10.1246/cl.140275
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn-2(H2O)(2)] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.
引用
收藏
页码:1161 / 1163
页数:3
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