Rod-like carbon-coated MnS derived from metal-organic frameworks as high-performance anode material for sodium-ion batteries

被引：50
|
作者：
Gao, Xiaoyan [1 ]
Zhang, Xiaojie [1 ]
Jiang, Jinlong [1 ]
Chen, Jing [1 ]
机构：
[1] Huaiyin Inst Technol, Sch Chem Engn, Key Lab Palygorskite Sci & Appl Technol Jiangsu, Huaian 223003, Jiangsu, Peoples R China
来源：
MATERIALS LETTERS | 2018年 / 228卷
基金：
中国国家自然科学基金;
关键词：
Rod-like MnS/C hybrid; Metal-organic frameworks; Sodium-ion batteries; Energy storage and conversion; Composite materials; INITIAL COULOMBIC EFFICIENCY; LONG-LIFE; HIGH-CAPACITY; MICROSPHERES; COMPOSITE; OXIDE;
D O I：
10.1016/j.matlet.2018.05.077
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel rod-like carbon-coated MnS electrode material (MnS/C) hybrid for sodium ions batteries (SIBs) was designed by annealing Mn-based metal-organic frameworks coupled with sulfur. When evaluated as anode material for SIBs, the typical MnS/C hybrid exhibits satisfied reversible capacity of 297 mAh g(-1) after 100 cycles at 50 mA g(-1), excellent rate capability (173.9 mAh g(-1) at 1 Ag-1 and 143.1 mAh g(-1) at 2.5 A g(-1)) and robust long-term cycling stability (148.3 mAh g(-1) after 5000 cycles at 1 A g(-1)), showing great potential for high-performance SIBs. (C) 2018 Published by Elsevier B.V.
引用
收藏
页码：42 / 45
页数：4
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