Growth and Characterization of Hybrid Organolead Halide CH3NH3PbI3 Thin Films Prepared by Single Source Thermal Evaporation

被引：0

作者：

Fan Ping ^{[1
,2
]}

Gu Di ^{[1
]}

Liang Guang-Xing ^{[1
,2
]}

Luo Jing-Ting ^{[1
,2
]}

Zhang Dong-Ping ^{[1
,2
]}

Chen Ju-Long ^{[1
]}

机构：

[1] Shenzhen Univ, Inst Thin Film Phys & Applicat, Coll Phys Sci & Technol, Shenzhen 518060, Peoples R China

[2] Shenzhen Univ, Shenzhen Key Lab Sensor Technol, Shenzhen 518060, Peoples R China

来源：

JOURNAL OF INORGANIC MATERIALS | 2015年 / 30卷 / 10期

基金：

中国国家自然科学基金;

关键词：

thermal evaporation; CH3NH3PbI3 thin films; perovskite solar cell; microstructure; PEROVSKITE SOLAR-CELLS;

D O I：

暂无

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Hybrid organolead halide CH3NH3PbI3 thin films were prepared by thermal evaporation with single source. The microstructure, composition, surface morphology and optical properties of the thin films were characterized by X-ray diffractometry (XRD), X-ray dispersive spectroscope (EDS), scanning electron microscope (SEM) and spectrophotometer technique, respectively. The comparison on properties for the films prepared by different methods (thermal evaporation and spin coating) was illustrated. Compared to the film prepared by spin coating, uniform, the nonporous and complete surface coverage perovskite thin film with high level of phase purity and good crystallization is formed by single source thermal evaporation. A direct bandgap of 1.57 eV for CH3NH3PbI3 thin films is obtained which makes this material to be a good light absorber.

引用

页码：1105 / 1109

页数：5

共 13 条

[1] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[2] Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].

Burschka, Julian ;

Pellet, Norman ;

Moon, Soo-Jin ;

Humphry-Baker, Robin ;

Gao, Peng ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

NATURE, 2013, 499 (7458) :316-+

[3] Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].

Chen, Qi ;

Zhou, Huanping ;

Hong, Ziruo ;

Luo, Song ;

Duan, Hsin-Sheng ;

Wang, Hsin-Hua ;

Liu, Yongsheng ;

Li, Gang ;

Yang, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625

[4] General Working Principles of CH3NH3PbX3 Perovskite Solar Cells [J].

Gonzalez-Pedro, Victoria ;

Juarez-Perez, Emilio J. ;

Arsyad, Waode-Sukmawati ;

Barea, Eva M. ;

Fabregat-Santiago, Francisco ;

Mora-Sero, Ivan ;

Bisquert, Juan .

NANO LETTERS, 2014, 14 (02) :888-893

[5] High efficiency perovskite solar cells: from complex nanostructure to planar heterojunction [J].

He, Ming ;

Zheng, Dajiang ;

Wang, Mengye ;

Lin, Changjian ;

Lin, Zhiqun .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (17) :5994-6003

[6] 6.5% efficient perovskite quantum-dot-sensitized solar cell [J].

Im, Jeong-Hyeok ;

Lee, Chang-Ryul ;

Lee, Jin-Wook ;

Park, Sang-Won ;

Park, Nam-Gyu .

NANOSCALE, 2011, 3 (10) :4088-4093

[7] Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells [J].

Kojima, Akihiro ;

Teshima, Kenjiro ;

Shirai, Yasuo ;

Miyasaka, Tsutomu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (17) :6050-+

[8] Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites [J].

Lee, Michael M. ;

Teuscher, Joel ;

Miyasaka, Tsutomu ;

Murakami, Takurou N. ;

Snaith, Henry J. .

SCIENCE, 2012, 338 (6107) :643-647

[9] Efficient planar heterojunction perovskite solar cells by vapour deposition [J].

Liu, Mingzhen ;

Johnston, Michael B. ;

Snaith, Henry J. .

NATURE, 2013, 501 (7467) :395-+

[10]

Malinkiewicz O, 2014, NAT PHOTONICS, V8, P128, DOI [10.1038/NPHOTON.2013.341, 10.1038/nphoton.2013.341]

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