2p correlation satellites in neon clusters investigated by photoemission

被引:15
作者
Joshi, S. [1 ]
Barth, S. [1 ]
Marburger, S. [1 ]
Ulrich, V. [1 ]
Hergenhahn, U. [1 ]
机构
[1] EURATOM, Max Planck Inst Plasmaphys, D-85748 Garching, Germany
关键词
D O I
10.1103/PhysRevB.73.235404
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Photoelectron spectra of the 2p correlation satellites in free Ne clusters have been measured for a number of cluster sizes. With the exception of the least strongly bound prominent satellite line, derived from the 2p(4)(D-1)3s atomic configuration, the satellites in the cluster show a broadening with the increase of cluster size, but no pronounced energy shift with respect to the atomic lines. The 2p(4)(D-1)3s satellite has peculiar properties that are analyzed in detail: We find a small monomer-cluster shift of the binding energy, but no splitting of the satellite in a bulk and a surface component. Final state mechanisms that could lead to this behavior, which differs significantly from the main valence photoelectron lines, are discussed.
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页数:7
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