Cationic triangulenes and helicenes: synthesis, chemical stability, optical properties and extended applications of these unusual dyes

被引：208

作者：

Bosson, Johann ^{[1
]}

Gouin, Jerome ^{[1
]}

Lacour, Jerome ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

来源：

CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 08期

基金：

瑞士国家科学基金会;

关键词：

ION-PAIR FORMATION; ELECTRON-TRANSFER; TRIOXATRIANGULENIUM ION; CIRCULAR-DICHROISM; RESOLUTION; BINDING; STATE; DNA; FUNCTIONALIZATION; TRIOXATRICORNAN;

D O I：

10.1039/c3cs60461f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cationic triangulenes and helicenes are highly stable carbocations with planar and helical conformations respectively. These moieties are effective dyes with original absorption and emission properties. Over the last decade, they have received greater attention and are considered as valuable tools for the development of innovative applications. In this review, the synthesis of these unique compounds is presented together with their core chemical and physical properties. Representative applications spanning from surface sciences to biology and chemistry are presented.

引用

页码：2824 / 2840

页数：17

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