Acetylacetone-Fe catalyst modified by imidazole ionic compound and its application in aerobic oxidation of β-isophorone

被引：33

作者：

Hu, Xingbang ^{[1
]}

Mao, Jianyong ^{[1
]}

Sun, Yong ^{[1
]}

Chen, Hang ^{[1
]}

Li, Haoran ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2009年 / 10卷 / 14期

基金：

中国国家自然科学基金;

关键词：

Ionic compound; Acetylacetone-Fe; Oxidation; Isophorone; MOLECULAR-OXYGEN; LIQUID; TRIMETHYL-1,4-BENZOQUINONE; 2,3,6-TRIMETHYLPHENOL; EPOXIDATION; HYDROGEN; SILICA; TETRASULFOPHTHALOCYANINE; COMPLEXES; EFFICIENT;

D O I：

10.1016/j.catcom.2009.06.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Traditional acetylacetone-Fe catalyst modified by imidazole ionic compound was synthesized and used in the oxidation of beta-isophorone. Compared with the traditional acetylacetone-Fe, it was found that the modified acetylacetone-Fe catalyst was reusable, more effective and stable. which provides a new way for making more powerful and greener acetylacetone metal catalyst for chemical industry. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1908 / 1912

页数：5

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