Electrospinning Preparation of Nanosilicon/Disordered Carbon Composite as Anode Materials in Li-Ion Battery

被引：35

作者：

Fan, Xing ^{[1
]}

Zou, Lin ^{[1
]}

Zheng, Yong-Ping ^{[1
]}

Kang, Fei-Yu ^{[1
]}

Shen, Wan-Ci ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2009年 / 12卷 / 10期

基金：

中国国家自然科学基金;

关键词：

SECONDARY BATTERIES; NEGATIVE ELECTRODE; SILICON ANODES; LITHIUM; SI; NANOCOMPOSITES; NANOFIBER; GRAPHITE;

D O I：

10.1149/1.3186642

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrospinning is employed to prepare Si/C composite anode materials. By electrospinning of Si-poly(vinyl alcohol) and by subsequent pyrolysis under argon flow, the nanosilicon particles coated by disordered carbon are uniformly and tightly embedded in the irregular porous network of a disordered carbon matrix, which leads to the gradual release of large capacity from the pure Si component in the composite anode. After 50 cycles, the reversible discharge capacity of the Si/C composite can reach as high as 892.5 mAh/g. (C) 2009 The Electrochemical Society. [DOI: 10.1149/1.3186642] All rights reserved.

引用

页码：A199 / A201

页数：3

共 21 条

[1]

A Net, 2003, J POWER SOURCES, V95, P119

[2] Silicon, graphite and resin based hard carbon nanocomposite anodes for lithium ion batteries [J].

Datta, Moni Kanchan ;

Kumta, Prashant N. .

JOURNAL OF POWER SOURCES, 2007, 165 (01) :368-378

[3] Structured silicon anodes for lithium battery applications [J].

Green, M ;

Fielder, E ;

Scrosati, B ;

Wachtler, M ;

Serra Moreno, J .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (05) :A75-A79

[4] On the irreversible capacities of disordered carbons in lithium-ion rechargeable batteries [J].

Guerin, K ;

Fevrier-Bouvier, A ;

Flandrois, S ;

Simon, B ;

Biensan, P .

ELECTROCHIMICA ACTA, 2000, 45 (10) :1607-1615

[5] Silicon/disordered carbon nanocomposites for lithium-ion battery anodes [J].

Guo, ZP ;

Milin, E ;

Wang, JZ ;

Chen, J ;

Liu, HK .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2211-A2216

[6] Study of silicon/polypyrrole composite as anode materials for Li-ion batteries [J].

Guo, ZP ;

Wang, JZ ;

Liu, HK ;

Dou, SX .

JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :448-451

[7] Chemical vapor deposited silicon/graphite compound material as negative electrode for lithium-ion batteries [J].

Holzapfel, M ;

Buqa, H ;

Krumeich, F ;

Novák, P ;

Petrat, FM ;

Veit, C .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (10) :A516-A520

[8] Si-carbon core-shell composite anode in lithium secondary batteries [J].

Jung, Yoon Seok ;

Lee, Kyu T. ;

Oh, Seung M. .

ELECTROCHIMICA ACTA, 2007, 52 (24) :7061-7067

[9] Fabrication of electrospinning-derived carbon nanofiber webs for the anode material of lithium-ion secondary batteries [J].

Kim, Chan ;

Yang, Kap Seung ;

Kojima, Masahito ;

Yoshida, Kazuto ;

Kim, Yong Jung ;

Kim, Yoong Ahm ;

Endo, Morinobu .

ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (18) :2393-2397

[10] An in situ X-ray diffraction study of the reaction of Li with crystalline Si [J].

Li, Jing ;

Dahn, J. R. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :A156-A161

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