Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications

被引：10

作者：

Balcar, Hynek ^{[1
]}

Shinde, Tushar ^{[1
]}

Lamac, Martin ^{[1
]}

Sedlacek, Jan ^{[2
]}

Zednik, Jiri ^{[2
]}

机构：

[1] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Vvi, CR-18223 Prague 8, Czech Republic

[2] Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Prague 12840 2, Albertov, Czech Republic

来源：

JOURNAL OF POLYMER RESEARCH | 2014年 / 21卷 / 09期

关键词：

Poly (vinylnorbornene); Ring-opening metathesis polymerization; Post-polymerization modification; Olefin metathesis; Ene-yne metathesis; MESOPOROUS MOLECULAR-SIEVES; C-13; NMR-SPECTRA; ADDITION POLYMERIZATION; NORBORNENE; CATALYST; 5-VINYL-2-NORBORNENE; ROMP; DERIVATIVES; COMPLEXES; EFFICIENT;

D O I：

10.1007/s10965-014-0557-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ring-opening metathesis polymerization of vinylnorbornene with molybdenum (VI) complex or with Hoveyda-Grubbs type Ru alkylidene complex provided soluble polymers, poly (VNBE)s of M (n) about 10 000, having vinyl pendant groups on cyclopentenylenevinylene main chains. Post-polymerization modification via cross-metathesis of pendant vinyl groups with cis-1,4-diacetoxybut-2-ene, 5-hexenyl acetate, allyl acetoacetate, and allyltrimethylsilane was accomplished. Functionalization of poly (VNBE) was also performed via ene-yne cross-metathesis of vinyl pendants with (4-fluorophenyl) acetylene and (2,4-difluorophenyl) acetylene.

引用

页数：8

共 26 条

[11] Novel, efficient, palladium-based system for the polymerization of norbornene derivatives: Scope and mechanism [J].

Hennis, AD ;

Polley, JD ;

Long, GS ;

Sen, A ;

Yandulov, D ;

Lipian, J ;

Benedikt, GM ;

Rhodes, LF ;

Huffman, J .

ORGANOMETALLICS, 2001, 20 (13) :2802-2812

[12] C-13 NMR-SPECTRA OF POLYMERS MADE BY RING-OPENING POLYMERIZATION OF (+/-) AND (+)-EXO-5-METHYLBICYCLO[2.2.1]HEPT-2-ENE USING METATHESIS CATALYSTS [J].

IVIN, KJ ;

LAPIENIS, G ;

ROONEY, JJ .

POLYMER, 1980, 21 (04) :436-443

[13]

IVIN KJ, 1981, MAKROMOL CHEM, V182, P1847

[14]

Ivin KJ., 1997, Olefin Metathesis and Metathesis Polymerization

[15] A recyclable Ru-based metathesis catalyst [J].

Kingsbury, JS ;

Harrity, JPA ;

Bonitatebus, PJ ;

Hoveyda, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (04) :791-799

[16] Synthesis and ROMP activity of aminophenol-substituted tungsten(VI) and molybdenum(VI) complexes [J].

Lehtonen, Ari ;

Balcar, Hynek ;

Sedlacek, Jan ;

Sillanpaa, Reijo .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (07) :1171-1176

[17] Industrial applications of olefin metathesis [J].

Mol, JC .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 213 (01) :39-45

[18] Ring-Opening Polymerization of THF by Aryloxo-Modified (Imido)vanadium(V)-alkyl Complexes and Ring-Opening Metathesis Polymerization by Highly Active V(CHSiMe3)(NAd)(OC6F5)(PMe3)2 [J].

Nomura, Kotohiro ;

Suzuki, Ken ;

Katao, Shohei ;

Matsumoto, Yuichi .

ORGANOMETALLICS, 2012, 31 (14) :5114-5120

[19]

Osokin YG, 2007, PETROL CHEM+, V47, P1, DOI 10.1134/S096554410701001X

[20] Addition polymerization of norbornene, 5-vinyl-2-norbornene and 2-methoxycarbonyl-5-norbornene with a catalyst based on a palladium(0) precursor complex [J].

Saito, Tatsuya ;

Wakatsuki, Yasuo .

POLYMER, 2012, 53 (02) :308-315

← 1 2 3 →