Synthesis and crystal structures of [P(C6H5)(4)][1-(NH3)B10H9] and Cs[(NH3)B12H11]center dot 2CH(3)OH

被引：18

作者：

Nachtigal, C ^{[1
]}

Haeckel, O ^{[1
]}

Preetz, W ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 09期

关键词：

1-ammine-nonahydro-closo-decaborate(1-) ammine-undecahydro-closo-dodecaborate(1-); crystal structure;

D O I：

10.1002/zaac.19976230911

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reduction of [1-(NO2)B10H9](2-) with aluminum in alkaline solution yields [1-(NH3)B10H9](-) and by treatment of [B12H12](2-) with hydroxylamine-O-sulfonic acid [(NH3)B12H11](-) is formed. The crystal structures of [P(C6H5)(4)][1-(NH3)B10H9] (triclinic, space group P (1) over bar, a = 7.491(2), b = 13.341(2), c = 14.235(1) Angstrom, alpha = 68.127(9), beta = 81.85(2), gamma = 86.860(3)degrees, Z = 2) and CS[(NH3)B12H11].2CH(3)OH (monoclinic, space group P2(1)/n, a = 14.570(2), b = 7.796(1), c = 15.076(2) Angstrom, beta = 111.801(8)degrees, Z = 4) reveal for both compounds the bonding of an ammine substituent to the cluster anion.

引用

页码：1385 / 1388

页数：4

共 13 条

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