Metal-Ligand Misfits: Facile Access to Rhenium-Oxo Corroles by Oxidative Metalation

被引：59

作者：

Einrem, Rune F. ^{[1
]}

Gagnon, Kevin J. ^{[2
]}

Alemayehu, Abraham B. ^{[1
]}

Ghosh, Abhik ^{[1
]}

机构：

[1] UiT Arctic Univ Norway, Dept Chem, N-9037 Tromso, Norway

[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 02期

关键词：

corroles; oxidation; metalation; rhenium; size mismatch; BOND COVALENT RADII; ELECTRONIC ABSORPTION; MESO-TRIARYLCORROLES; NONINNOCENT; COMPLEXES; REACTIVITY; CHEMISTRY; INNOCENT; IRON;

D O I：

10.1002/chem.201504307

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With the exception of a single accidental synthesis, rhenium corroles are unknown, but of great interest as catalysts and potential radiopharmaceuticals. Oxidative metalation of meso-triarylcorroles with [Re-2(CO)(10)] in refluxing decalin has provided a facile and relatively high-yielding route to rhenium(V)-oxo corroles. The complexes synthesized could all be fully characterized by single-crystal X-ray structure analyses.

引用

页码：517 / 520

页数：4

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