Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4+2] cycloaddition

被引：62

作者：

Aikawa, Kohsuke ^{[1
]}

Akutagawa, Susumu ^{[1
]}

Mikami, Koichi ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Tokyo 1528552, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 39期

关键词：

D O I：

10.1021/ja0650100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High enantioselective [4 + 2] cycloaddition can be achieved by cationic Rh complexes bearing not only chiral phosphine but also chiral diene. This is the first example of asymmetric synergy between chiral dienes and diphosphines. Copyright © 2006 American Chemical Society.

引用

页码：12648 / 12649

页数：2

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