Synthesis and structure of the novel octanuclear lithium aryloxide cluster [(hmqLi)8(THF)4] (hmq-=2-hydroxy-4-methylquinoline monoanion):: formation of a rare four-rung intercepted Li-O ladder

被引:9
作者
Liddle, ST [1 ]
Clegg, W [1 ]
机构
[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 21期
关键词
D O I
10.1039/b206894j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title complex, readily prepared by the facile deprotonation of 2-hydroxy-4-methylquinoline by n-butyllithium in ethereal solvent, crystallises as a novel octanuclear cluster constructed around a rare intercepted four-rung Li-O ladder.
引用
收藏
页码:3923 / 3924
页数:2
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