Formation of a one-dimensional helical alignment of water molecules within a water-mediated supramolecular helix using molecular self-assembly of a water-soluble short pseudopeptide

被引:13
|
作者
Guha, Samit
Drew, Michael G. B.
Banerjee, Arindam [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Biol Chem, Kolkata 700032, W Bengal, India
[2] Univ Reading, Sch Chem, Reading RG6 6AD, Berks, England
基金
英国工程与自然科学研究理事会;
关键词
supramolecular chemistry; pseudopeptide; turn; helix;
D O I
10.1016/j.tetlet.2006.08.132
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reported pseudopeptide 1 adopts a double turn molecular conformation consisting of an intramolecular 9-membered turn together with a water-mediated 11-atom turn and this pseudopeptide 1 self-assembles to form a water-mediated supramolecular helical structure with internal water molecules, which are aligned in a ID helical array. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7951 / 7955
页数:5
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