Highly enantioselective iron-catalyzed sulfide oxidation with aqueous hydrogen peroxide under simple reaction conditions

被引：211

作者：

Legros, J ^{[1
]}

Bolm, C ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 32期

关键词：

asymmetric catalysis; iron; oxidation; peroxides; sulfoxides;

D O I：

10.1002/anie.200460236

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An attractive alternative to the currently existing methods for the metal-catalyzed oxidation of sulfides to sulfoxides is asymmetric iron-catalyzed oxidation with hydrogen peroxide as the terminal oxidant (see scheme). In the presence of a benzoic acid derivative, this simple process provides sulfoxides with up to 96% ee in moderate to good yields (up to 78%).

引用

页码：4225 / 4228

页数：4

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