Highly enantioselective iron-catalyzed sulfide oxidation with aqueous hydrogen peroxide under simple reaction conditions

被引：211
|
作者：
Legros, J [1 ]
Bolm, C [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 32期
关键词：
asymmetric catalysis; iron; oxidation; peroxides; sulfoxides;
D O I：
10.1002/anie.200460236
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An attractive alternative to the currently existing methods for the metal-catalyzed oxidation of sulfides to sulfoxides is asymmetric iron-catalyzed oxidation with hydrogen peroxide as the terminal oxidant (see scheme). In the presence of a benzoic acid derivative, this simple process provides sulfoxides with up to 96% ee in moderate to good yields (up to 78%).
引用
收藏
页码：4225 / 4228
页数：4
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