A New 4-Connected Co(II) Coordination Framework With an Uncommon Two-Fold Interpenetrating Net: Synthesis, Structure and Luminescence Property

被引：9
|
作者：
Guo, Feng [1 ]
机构：
[1] Dezhou Univ, Dept Chem, Dezhou 253023, Shandong, Peoples R China
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2009年 / 19卷 / 03期
关键词：
Coordination polymer; Co(II); Crystal structure; Luminescence; FLEXIBLE BIS(IMIDAZOLE) LIGANDS; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; PHOTOLUMINESCENCE; CADMIUM(II); NETWORKS; POLYMERS; DICARBOXYLATES; COMPLEXES; CLUSTERS;
D O I：
10.1007/s10904-009-9272-x
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The coordination polymer [Co(pbc)(2)(H(2)O)](n)(Hpbc = 3-Pyrid-4-ylbenzoic acid) was prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, FTIR spectra and element analysis. X-ray diffraction analysis reveals that the pbc(-) ligands act as diconnectors to link two Co(II) centers and adopt a two coordination mode: mu (2)-N, O and mu (2)-N, O, O to form infinite wavy cobalt-carboxylate chains along the bc plane. Furthermore, compound, [Co(pbc)(2)(H(2)O)](n), shows intense photoluminescence at room temperature.
引用
收藏
页码：406 / 409
页数：4
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