The synthesis of metal-organic framework Al-MIL-53-derived Bronsted acid catalyst and its application in the Mannich reaction

被引：12

作者：

Miao, Zongcheng ^{[1
]}

Qi, Chao ^{[2
]}

Wang, Liangshi ^{[3
]}

Wensley, Allison M. ^{[2
]}

Luan, Yi ^{[2
]}

机构：

[1] Xijing Univ, Xian 710123, Shaanxi Provinc, Peoples R China

[2] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, 30 Xueyuan Rd, Beijing 100083, Peoples R China

[3] Natl Engn Res Ctr Rare Earth Mat, Gen Res Inst Nonferrous Met, Beijing 100088, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2017年 / 31卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Bronsted acid; heterogeneous catalysis; Mannich reaction; metal-organic framework; sulfonic acid; SULFONIC-ACID; PERFORMANCE; GENERATION;

D O I：

10.1002/aoc.3569

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A metal-organic framework Al-MIL-53-NH2-derived Bronsted acid catalyst (Al-MIL-53-RSO3H) has been synthesized employing a post-synthetic modification strategy under mild conditions. The Al-MIL-53-RSO3H catalyst was successfully utilized in the nitro-Mannich reaction taking advantage of its strong Bronsted acidity. Good to excellent yields of Mannich adducts were achieved for a variety of acylimine substrates in the presence of 0.1 mol% Al-MIL-53-RSO3H. Furthermore, the Al-MIL-53-RSO3H catalyst can be recycled five times without decreasing the yield and selectivity of Mannich adducts.

引用

页数：5

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