Synthesis and Properties of 1-[2,5-dimethyl-3-thienyl]-2-[2-methyl-5-(p-N,N-dimethylaminophenyl)-3-thienyl]perfluorocyclopentene

被引:0
作者
Liao, Guanming [1 ]
Sun, Zhiyuan [1 ]
Pu, Shouzhi [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源
ADVANCED RESEARCH ON MATERIAL SCIENCE, ENVIROMENT SCIENCE AND COMPUTER SCIENCE III | 2014年 / 886卷
关键词
Diarylethene; Photochromism; Kinetic; Fluorescence; DIARYLETHENES; PHOTOCHROMISM;
D O I
10.4028/www.scientific.net/AMR.886.155
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An asymmetrical photochromic diarylethene 1-[2,5-dimethyl -3-thienyl]-2-[2-methyl-5-(p-N,N-dimethylaminophenyl)-3-thienyl]perfluorocyclopentene was synthesized and its photochemical properties were investigated in detail. The results demonstrated that the compound has excellent photochromic properties and good fluoresence. The cyclization/cycloreversion process of the compound was determined to be the zeroth/first order reaction. The fluorescence intensity increased with increasing concentration, but when the concentration increased enough high, the fluorescence intensity decreased rapidly.
引用
收藏
页码:155 / 158
页数:4
相关论文
共 13 条
[1]   Remote-Control Photoswitching Using NIR Light [J].
Carling, Carl-Johan ;
Boyer, John-Christopher ;
Branda, Neil R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10838-+
[2]   Fluorescence of photochromic 1,2-bis(3-methyl-2-thienyl)ethene [J].
Fukaminato, T ;
Kawai, T ;
Kobatake, S ;
Irie, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (33) :8372-8377
[3]   Full-color photochromism of a fused dithienylethene trimer [J].
Higashiguchi, K ;
Matsuda, K ;
Tanifuji, N ;
Irie, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) :8922-8923
[4]   Diarylethenes for memories and switches [J].
Irie, M .
CHEMICAL REVIEWS, 2000, 100 (05) :1685-1716
[5]   Three-dimensional optical data storage using photochromic materials [J].
Kawata, S ;
Kawata, Y .
CHEMICAL REVIEWS, 2000, 100 (05) :1777-1788
[6]   Photochromism of Asymmetrical Diarylethenes with a Pyrrole Unit: Effects of Aromatic Stabilization Energies of Aryl Rings [J].
Liu, Gang ;
Pu, Shouzhi ;
Wang, Renjie .
ORGANIC LETTERS, 2013, 15 (05) :980-983
[7]   Recent progress on photochromic diarylethene polymers [J].
Luo, Qianfu ;
Cheng, Hui ;
Tian, He .
POLYMER CHEMISTRY, 2011, 2 (11) :2435-2443
[8]   Diarylethene as a photo switching unit [J].
Matsuda, K ;
Irie, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2004, 5 (02) :169-182
[9]   Photochromism and optical property of gold nanoparticles covered with low-polydispersity diarylethene polymers [J].
Nishi, Hiroyasu ;
Kobatake, Seiya .
MACROMOLECULES, 2008, 41 (11) :3995-4002
[10]   Efficient synthesis and properties of isomeric photochromic diarylethenes having a pyrrole unit [J].
Pu, Shouzhi ;
Liu, Gang ;
Shen, Liang ;
Xu, Jingkun .
ORGANIC LETTERS, 2007, 9 (11) :2139-2142