Spectroscopic characterization of a phenolate bound FeII-O2 adduct: gauging the relative "push" effect of a phenolate axial ligand

被引：21

作者：

Das, Pradip Kumar ^{[1
]}

Mittra, Kaustuv ^{[1
]}

Dey, Abhishek ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata, India

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 40期

关键词：

RESONANCE RAMAN-SPECTRA; ELECTRON REDUCTION; O-2; BINDING; O-O; CYTOCHROME-P450; COMPLEXES; DIOXYGEN; HEMOGLOBIN; MYOGLOBIN; INTERMEDIATE;

D O I：

10.1039/c3cc47528j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxygen adducts of solvent, imidazole and phenolate bound iron porphyrin complexes are reported. The data show that the Fe-O vibration of the Fe-O-2 species shifts from 584 cm(-1) to 570 cm(-1) as neutral axial ligands are replaced by the anionic phenolate ligand.

引用

页码：5218 / 5220

页数：3

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