Chromium (III) complexes of azo dye ligands: Synthesis, characterization, DNA binding and application studies

被引:12
作者
Abbas, Nasir [1 ]
Tirmizi, Syed Ahmad [1 ]
Shabir, Ghulam [1 ]
Saeed, Aamer [1 ]
Hussain, Ghulam [4 ]
Channer, Pervaiz Ali [1 ]
Saleem, Rashid [2 ]
Ayaz, Muhammad [3 ]
机构
[1] Quaid I Azam Univ, Dept Chem, Islamabad, Pakistan
[2] Leather Div Shafi Reso Chem, Lahore, Pakistan
[3] CECOS Univ IT & Emerging Sci, Peshawar, Pakistan
[4] Univ Punjab, Inst Chem, Lahore, Pakistan
关键词
Complexes; DNA binding; electronic spectroscopy; intercalation mode;
D O I
10.1080/24701556.2017.1357632
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chromium (III) complexes of Azo dyes ligands envisaged on novel synthesized 4-Amino-1-(p-sulphophenyl)-3-methyl-5-pyrazolone diazonium salt coupled with different phenolic couplers appended on diverse substituents. The complexes have been characterized by elemental analysis, UV, FTIR and NMR studies. The DNA studies have been investigated for complexes by electronic absorption spectroscopy. The results have shown that chromium (III) complexes bind to DNA through intercalation mode. Synthesized Chromium complexes have been applied on leather to check their serviceability and they exhibited moderate to high values of light fastness and perspiration fastness (4-5).
引用
收藏
页码:57 / 66
页数:10
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